Adsorption of Inhalation Anesthetics (Fluranes and Ethers) on Activated Carbons and Zeolites at Trace Level Concentrations

Adsorption of Inhalation Anesthetics (Fluranes and Ethers) on Activated Carbons and Zeolites at Trace Level Concentrations
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微量浓度的吸入麻醉剂(氟烷和醚)在活性炭和沸石上的吸附

DOI:
10.1021/acs.jced.7b00079
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发表时间:
2017
影响因子:
--
通讯作者:
D. Bathen
D. Bathen
中科院分区:
工程技术3区
文献类型:
--
作者:
D. Bucher;C. Pasel;M. Luckas;D. Bathen

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本文介绍了卤代醚(地氟烷,异氟烷,七氟烷),这是用作吸入麻醉剂,和脂肪族醚(乙醚和甲基丙基醚)从氮载气流的吸附等温线和解吸数据。在25 °C和1巴下测量等温线。在25至250 °C的温度下分析解吸。以不同结构和铝含量的沸石和不同孔径分布的活性炭为吸附剂。对吸附等温线和脱附数据的分析着重于吸附分子与吸附剂表面之间的相互作用。我们讨论了吸附剂的分子结构和极性以及吸附剂的孔结构和表面化学的具体影响。
This paper presents adsorption isotherms and desorption data of halogenated ethers (desflurane, isoflurane, and sevoflurane), which are used as inhalation anesthetics, and aliphatic ethers (diethyl ether and methyl propyl ether) from a nitrogen carrier gas stream. The isotherms were measured at 25 °C and 1 bar. Desorption was analyzed at temperatures between 25 and 250 °C. Zeolites with different structure and aluminum content as well as activated carbons with different pore size distributions were used as adsorbents. The analysis of the adsorption isotherms and the desorption data focuses on the interactions between adsorptive molecules and adsorbents’ surfaces. We discuss the specific influence of the molecular structure and polarity of the adsorptives as well as of the pore structure and surface chemistry of the adsorbents.
DOI: 10.1002/cite.201600052
发表时间: 2016
影响因子: 1.9
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