Host-guest supramolecular chemistry at solid-liquid interface: An important strategy for preparing two-dimensional functional nanostructures

Host-guest supramolecular chemistry at solid-liquid interface: An important strategy for preparing two-dimensional functional nanostructures
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固液界面主客体超分子化学:制备二维功能纳米结构的重要策略

DOI:
10.1007/s11426-013-4975-9
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发表时间:
2014
期刊:
Science China Chemistry
影响因子:
--
通讯作者:
Wang, Chen
Wang, Chen
中科院分区:
其他
文献类型:
--
作者:
Zhang, Xuemei;Zeng, Qingdao;Wang, Chen

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超分子自组装是纳米技术中的一种重要策略,近二十年来得到了广泛的研究。本文综述了近年来利用主-客体超分子化学技术在固-液界面上构建二维纳米结构的研究进展,并着重介绍了主组装体与客体分子之间的相互作用。首先讨论了连接杂化结构的氢键。然后,我们密切关注了最近在直接制备结构复杂性日益增加的新型纳米结构方面蓬勃发展的表面限制缩合反应。最后,对二维超分子主客体结构的腔约束进行了研究。在上述相互作用的基础上,制备了一组功能杂化结构。值得注意的是,扫描隧道显微镜(STM)是一种在单分子水平上探测表面形貌和信息的独特技术,已被用于探测高取向热解石墨(HOPG)表面形成的结构。
Supramolecular self-assembly, an important strategy in nanotechnology, has been widely studied in the past two decades. In this review, we have introduced the recent progress on construction of two-dimensional (2D) nanostructures by host-guest supramolecular chemistry at solid-liquid interface, and the interactions between the host assembly and the guest molecules are the major concerns. At first, the hydrogen bonds connected hybrid structures are discussed. And then we have paid a close attention on the surface-confined condensation reactions that has flourished recently in direct preparing novel nanostructures with increasing structural complexity. In the end, the cavity confinement of the 2D supramolecular host-guest architectures has been studied. On the basis of the above-mentioned interactions, a group of functional hybrid structures have been prepared. Notably, scanning tunneling microscopy (STM), a unique technique to probe the surface morphology and information at the single molecule level, has been used to probe the formed structures on highly oriented pyrolytic graphite (HOPG) surface.
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