Exceptional Adsorption and Binding of Sulfur Dioxide in a Robust Zirconium-Based Metal-Organic Framework.

Exceptional Adsorption and Binding of Sulfur Dioxide in a Robust Zirconium-Based Metal-Organic Framework.
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DOI:
10.1021/jacs.8b08433
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发表时间:
2018-11-21
影响因子:
15
通讯作者:
Schröder M
Schröder M
中科院分区:
化学1区
文献类型:
--
作者:
Carter JH;Han X;Moreau FY;da Silva I;Nevin A;Godfrey HGW;Tang CC;Yang S;Schröder M

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我们报告了创纪录的高SO2吸附容量为12.3 mmol g-1的强大的多孔材料,MFM-601,在298 K和1.0巴。MFM-601对SO2的吸附是完全可逆的,对CO2和N2具有高度选择性。在MFM-601中吸附的SO2和CO2分子的结合域已被确定通过原位同步辐射X射线衍射实验,在分子水平上观察到的高选择性的基础上提供见解。
We report a record-high SO2 adsorption capacity of 12.3 mmol g–1 in a robust porous material, MFM-601, at 298 K and 1.0 bar. SO2 adsorption in MFM-601 is fully reversible and highly selective over CO2 and N2. The binding domains for adsorbed SO2 and CO2 molecules in MFM-601 have been determined by in situ synchrotron X-ray diffraction experiments, giving insights at the molecular level to the basis of the observed high selectivity.
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