Synthesis and Characterization of Iron(II) Thiocyanate Complexes with Derivatives of the Tris(pyridine-2-ylmethyl)amine (tmpa) Ligand †‡
Synthesis and Characterization of Iron(II) Thiocyanate Complexes with Derivatives of the Tris(pyridine-2-ylmethyl)amine (tmpa) Ligand †‡
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硫氰酸铁 (II) 与三(吡啶-2-基甲基)胺 (tmpa) 配体衍生物配合物的合成和表征 †‡
DOI：
10.1002/zaac.201200237
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发表时间：
2012
期刊：
影响因子：
--
通讯作者：
S. Schindler
中科院分区：
文献类型：
--
作者：
S. Kisslinger;H. Kelm;S. Zheng;A. Beitat;Christian Würtele;R. Wortmann;S. Bonnet;S. Herres‐Pawlis;H. Krüger;S. Schindler
抽象的。合成并研究了一系列含有三脚架配体L[Fe(L)(Ncs)2](L=6-Me2tmpa，6-Me2pmea，6-Me2-uns-penp，6-Me2-uns-penp，Me2uns-penp，imine-uns-penp和tmg-uns-penp)的铁(II)二硫氰酸盐配合物[Fe(Tmpa)(Ncs)2]。对[Fe(6-Me2pmea)(NCS)2]、[Fe(6-Me2-Me2uns-penp)(NCS)2]、[Fe(Me2uns-penp)(NCS)2]、[Fe(imine-uns-penp)(NCS)2]和[Fe(TMG-uns-penp)(NCS)2]进行了结构表征。磁化率和穆斯堡尔谱测量表明，所有七个化合物在300-5K之间都保持了它们的高自旋态。
Abstract. A series of iron(II) dithiocyanate complexes containing the tripodal ligands L, [Fe(L)(NCS)2] (with L = 6-Me2tmpa, 6-Me2pmea, 6-Me2-Me2uns-penp, 6-Me2-uns-penp, Me2uns-penp, imine-uns-penp and TMG-uns-penp), analogous to the known SCO complex[Fe(tmpa)(NCS)2] were prepared and investigated. It was possible to structurally characterize [Fe(6-Me2pmea)(NCS)2], [Fe(6-Me2-Me2uns-penp)(NCS)2], [Fe(Me2uns-penp)(NCS)2], [Fe(imine-uns-penp)(NCS)2] and [Fe(TMG-uns-penp)(NCS)2]. Magnetic susceptibility and Mosbauer measurements showed that all seven compounds maintain their high-spin states between 300 and 5 K.
影响因子：
8.6
作者：
P. V. Koningsbruggen;Y. Maeda;H. Oshio
通讯作者：
P. V. Koningsbruggen;Y. Maeda;H. Oshio
影响因子：
13.3
作者：
Loew, Peter;Kim, Beomjoon;Bergaud, Christian
通讯作者：
Bergaud, Christian