Controlled synthesis and photocatalytic properties of porous hollow In2O3 microcubes with different sizes

Controlled synthesis and photocatalytic properties of porous hollow In2O3 microcubes with different sizes
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不同尺寸多孔空心In2O3微立方体的可控合成及其光催化性能

DOI:
10.1016/j.matchemphys.2011.08.013
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发表时间:
2011-11
影响因子:
4.6
通讯作者:
Yang, Heqing
Yang, Heqing
中科院分区:
材料科学3区
文献类型:
--
作者:
Zhao, Hua;Dong, Hongxing;Zhang, Lina;Wang, Xuewen;Yang, Heqing

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Uniform single-crystalline In(OH)3hollow microcubes have been synthesized in large quantities via a hydrothermal reaction of InCl3with NaF and ethylene glycol (EG) at 140–220°C for 12h. Porous In2O3hollow microcubes with a polycrystalline cubic structure can be obtained via calcining In(OH)3precursors at 400°C for 2h in air. Controlled Synthesis of In(OH)3and In2O3hollow microcubes with the average edge lengths in the range of 2.0–4.7μm can be achieved by changing the hydrothermal reaction temperature. The In(OH)3hollow microcubes were formed via an EG-assisted oriented attachment growth route using HF bubbles as the templates. Photocatalytic activities of the as-synthesized porous In2O3hollow microcubes were studied at room temperature. The results indicated that the hollow In2O3nanostructures display high photocatalytic activity in the photodegradation of rhodamine B and methyl orange.
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