Facile surfactant-thermal syntheses and characterization of quaternary copper thioantimonates(III) ACu(2)SbS(3) (A = K, Rb, Cs)

Facile surfactant-thermal syntheses and characterization of quaternary copper thioantimonates(III) ACu(2)SbS(3) (A = K, Rb, Cs)
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硫代锑酸铜(III) ACu(2)SbS(3) (A = K、Rb、Cs) 的简便表面活性剂热合成和表征

DOI:
10.1016/j.jallcom.2015.11.075
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发表时间:
2016-03
影响因子:
6.2
通讯作者:
Liu, Yi
Liu, Yi
中科院分区:
材料科学2区
文献类型:
--
作者:
Zhou, Chunmei;Chai, Wenxiang;Zhang, Qichun;Liu, Yi

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用表面活化-热合成法合成了三种新的硫代锑酸盐(Ⅲ)ACu_2SbS_3(A = K,Rb,Cs)。X射线单晶衍射分析表明,这三种化合物是同构的,具有二维层状结构。实验和理论研究都证实它们是具有窄带隙的半导体。我们的研究结果清楚地表明,表面活性剂,作为反应介质,可以提供令人兴奋的机会,探索新的多元硫属化合物具有不同的晶体结构和有趣的物理性质。
Three new quaternary thioantimonates(III) ACu2SbS3(A = K, Rb, Cs) have been prepared through the surfactant-thermal method. X-ray single crystal diffraction analysis reveals that these three compounds are isostructural and feature a two-dimensional layered structure. Both experimental and theoretical studies confirm they are semiconductors with narrow band gaps. Our results clearly indicated that surfactants, as reaction media, could offer exciting opportunities for exploring novel multinary chalcogenides with diverse crystal structures and interesting physical properties.
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