Recent progress in bipolar electropolymerization methods toward one-dimensional conducting polymer structures

Recent studies on electropolymerization methods toward onedimensional conducting polymer structures are summarized in this review. In particular, advanced techniques for templated electropolymerization of aromatic monomers, in which migration of monomers into nanopores of the template is highly enhanced by using electrophoretic effect, are described. For templateless approach, electric field-driven bipolar electropolymerization of 3,4-ethylenedioxythiophene monomer is introduced as a strong tool to fabricate the corresponding conducting polymer fibers and films grown in the direction of an applied electric field.

本综述总结了近期针对一维导电聚合物结构的电聚合方法的研究。特别描述了芳香族单体模板电聚合的先进技术，其中通过利用电泳效应大大增强了单体向模板纳米孔的迁移。对于无模板方法，介绍了3,4 - 乙撑二氧噻吩单体的电场驱动双极电聚合，它是一种用于制备在施加电场方向上生长的相应导电聚合物纤维和薄膜的有力工具。