Recent progress in oxynitride photocatalysts for visible-light-driven water splitting.

Recent progress in oxynitride photocatalysts for visible-light-driven water splitting.
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DOI:
10.1088/1468-6996/16/3/033506
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发表时间:
2015-06
影响因子:
5.5
通讯作者:
Domen K
Domen K
中科院分区:
材料科学2区
文献类型:
--
作者:
Takata T;Pan C;Domen K

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光催化水分解为氢和氧是一种将光能直接转化为可储存的化学能的方法,并且在大规模太阳能利用中的应用受到了相当大的关注。颗粒半导体通常用作光催化剂,并且半导体性质如带隙、能带位置和光载流子迁移率可以严重影响光催化性能。活性光催化剂的设计已经进行了考虑这样的半导体性能。光催化剂除了具有半导体性质外,还具有催化性质。控制表面氧化还原反应以有效产生目标反应物的能力对于光催化剂也是重要的。在过去的几十年中,已经开发了用于水裂解的各种光催化剂,并且最近主要关注的是用于水裂解的可见光敏感的光催化剂的开发。本文介绍了水分解光催化剂的研究进展,重点介绍了氮氧化合物光催化剂在可见光诱导水分解方面的研究进展。本文还讨论了设计用于水裂解的有效光催化剂的各种策略。
Photocatalytic water splitting into hydrogen and oxygen is a method to directly convert light energy into storable chemical energy, and has received considerable attention for use in large-scale solar energy utilization. Particulate semiconductors are generally used as photocatalysts, and semiconductor properties such as bandgap, band positions, and photocarrier mobility can heavily impact photocatalytic performance. The design of active photocatalysts has been performed with the consideration of such semiconductor properties. Photocatalysts have a catalytic aspect in addition to a semiconductor one. The ability to control surface redox reactions in order to efficiently produce targeted reactants is also important for photocatalysts. Over the past few decades, various photocatalysts for water splitting have been developed, and a recent main concern has been the development of visible-light sensitive photocatalysts for water splitting. This review introduces the study of water-splitting photocatalysts, with a focus on recent progress in visible-light induced overall water splitting on oxynitride photocatalysts. Various strategies for designing efficient photocatalysts for water splitting are also discussed herein.
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