Synthesis of nanosphere-like LiCoPO4 with excellent electrochemical performance via micro reactor assisted co-precipitation method

Synthesis of nanosphere-like LiCoPO4 with excellent electrochemical performance via micro reactor assisted co-precipitation method
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微反应器辅助共沉淀法合成具有优异电化学性能的纳米球LiCoPO4

DOI:
10.1142/s1793604718500376
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发表时间:
2018-10
影响因子:
1.3
通讯作者:
Yang Hui
Yang Hui
中科院分区:
材料科学4区
文献类型:
--
作者:
Zhao Huifang;Yu Yong;Wang Guojing;Chen Yunchao;Liu Xiaomin;Yang Hui

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Li3PO4 and Co3(PO[Formula: see text]8H2O precursors, precipitated within a micro reactor using ethyl alcohol as anti-solvent, are sintered to form nanosphere-like LiCoPO4. Even without carbon coating, the resulting sample with 2.1[Formula: see text]wt.% Li3PO4 existence presents surprisingly high initial discharge capacity (up to 164[Formula: see text]mAh/g and 787[Formula: see text]Wh/kg at 0.1C) and superior high rate performance (117[Formula: see text]mAh/g and 561[Formula: see text]Wh/kg at 5C).
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