Recent advances in syngas production from biomass catalytic gasification: A critical review on reactors, catalysts, catalytic mechanisms and mathematical models
Recent advances in syngas production from biomass catalytic gasification: A critical review on reactors, catalysts, catalytic mechanisms and mathematical models
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生物质催化气化合成气生产的最新进展：对反应器、催化剂、催化机制和数学模型的批判性评论
DOI：
10.1016/j.rser.2019.109426
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发表时间：
2019-12
影响因子：
15.9
通讯作者：
Xian-Yong Wei
中科院分区：
文献类型：
--
作者：
Jie Ren;Jing-Pei Cao;Xiao-Yan Zhao;Fei-Long Yang;Xian-Yong Wei
生物质气化转化为合成气，再经F-T合成制得其他化学物质，在可再生能源利用方面具有广阔的应用前景。尽管气化是一种可持续、环保的生物质增值利用技术，但焦油的生成是生物质气化过程中的主要问题。焦油可能会在反应堆上冷凝，然后堵塞和污染设备。优化后的气化炉和高效催化剂对生物质焦油的脱除是有效的。此外，焦油的生成机理和分解途径也是推进气化反应器优化和催化剂设计的重要因素。本文对气化炉类型、镍基催化剂、反应失活机理等基本原理进行了综述。综述了生物质催化气化的其他优良催化剂、有效气化炉和数学模型，并对催化剂反应机理和数学模型进行了详细的讨论。最后，对后续实验室和工业规模的研究进行了总结和展望。
Biomass gasification converts into syngas, then into other chemicalsviaFischer-Tropsch (F-T) synthesis is promising for renewable energy utilization. Although gasification is a sustainable and environmental-friendly technology for value-added utilization of biomass, tar formation is the major problem during the biomass gasification. Tar could condense on the reactor then block and foul equipment. An optimized gasifier and highly active catalyst were proved to be effective for biomass tar elimination. Furthermore, tar formation mechanism and the decomposition pathway were also important to advance the optimization of gasification reactors and catalyst design. This paper summarized the fundamentals, such as gasifier types, Ni-based catalyst, and reaction and deactivation mechanism. This review also sheds light on other excellent catalysts, effective gasifiers and mathematical models of biomass catalytic gasification, and catalyst reaction mechanisms and mathematical models are also discussed in detail. At last, the paper ends with a conclusion and prospective discussion to the latter lab and industrial-scale research.
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影响因子：
3.3
作者：
Borgschulte, Andreas;Gallandat, Noris;Zuettel, Andreas
通讯作者：
Zuettel, Andreas
影响因子：
2.7
作者：
P. Chaiprasert;T. Vitidsant
通讯作者：
P. Chaiprasert;T. Vitidsant
生物质热解挥发物催化重整褐铁矿富氢气体生产
影响因子：
5.3
作者：
Zhao Xiao-Yan;Ren Jie;Cao Jing-Pei;Wei Fu;Zhu Chen;Fan Xing;Zhao Yun-Peng;Wei Xian-Yong
通讯作者：
Wei Xian-Yong
影响因子：
7.5
作者：
J. Kihedu;Ryo Yoshiie;I. Naruse
通讯作者：
J. Kihedu;Ryo Yoshiie;I. Naruse
钛酸钠催化剂调节生物质产气提高H2/CO比脱焦油
影响因子：
8.7
作者：
Yuan Hongyou;Wu Shubin;Yin Xiuli;Huang Yanqin;Guo Daliang;Wu Chuangzhi
通讯作者：
Wu Chuangzhi