Understanding crystal nucleation in solution-segregated polymers
Understanding crystal nucleation in solution-segregated polymers
复制标题
了解溶液分离聚合物中的晶体成核
DOI:
10.1016/j.polymer.2009.06.005
复制
发表时间:
2009-07
期刊:
影响因子:
4.6
通讯作者:
Hu, Wenbing
中科院分区:
文献类型:
--
作者:
Zha, Liyun;Hu, Wenbing
We report dynamic Monte Carlo simulations of crystal nucleation in polymer bulk phase segregated from solutions. We found that poorer solvent enhances crystal nucleation in the concentrated phase of polymers. In addition, when the solvent becomes poor enough, crystal nucleation prefers to occur at the diffuse interfaces. The results are consistent with the predictions from theoretical phase diagrams, but something different from immiscible polymer blends. The surface-enhanced crystallization may explain the bowl-shaped crystal aggregates observed experimentally in poor solvent.
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影响因子:
4.6
作者:
C. Price;P. Harris;T. J. Holton;R. B. Stubbersfield
通讯作者:
C. Price;P. Harris;T. J. Holton;R. B. Stubbersfield
影响因子:
4.4
作者:
Wenbing Hu;D. Frenkel;V. Mathot
通讯作者:
Wenbing Hu;D. Frenkel;V. Mathot
影响因子:
5.5
作者:
Wenbing Hu;D. Frenkel
通讯作者:
Wenbing Hu;D. Frenkel
DOI:
10.1007/bf01500379
发表时间:
1965-08
期刊:
Kolloid-Zeitschrift und Zeitschrift für Polymere
影响因子:
--
作者:
I. L. Hay;A. Keller
通讯作者:
I. L. Hay;A. Keller
影响因子:
3
作者:
Gerald Oster
通讯作者:
Gerald Oster