Inhibitory effect of Ni-P coating on thermal expansion of carbon steel

Inhibitory effect of Ni-P coating on thermal expansion of carbon steel
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Ni-P镀层对碳钢热膨胀的抑制作用

DOI:
10.1016/j.surfcoat.2017.03.008
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发表时间:
2017-04
影响因子:
5.4
通讯作者:
Xiufang Bian
Xiufang Bian
中科院分区:
材料科学1区
文献类型:
--
作者:
Yinghui Yang;Shuai Liu;Jianguo Li;Xiufang Bian

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化学沉积Ni-P涂层可以抑制碳钢的热膨胀。镀后样品直径仅增加3%。衬底的热膨胀线性系数(CTE)由16 ppm/K降至12.68 ppm/K,降低率为20.72%。在613 K时,Ni-P涂层发生了体积收缩的结晶,这部分抵消了基体的热膨胀,从而产生了较小的CTE,这被称为结晶补偿机制。晶化后,在涂层与基体界面处形成以fei3为主的扩散层,FeNi3是NiFe Invar合金的初级相之一。该扩散层在抑制铁基体热膨胀中起关键作用,称为扩散层抑制机制。这些发现原则上适用于所有的亚铁合金,从而为降低亚铁合金的cte提供了一种潜在的简便方法。
The thermal expansion of carbon steel can be inhibited by electroless deposited Ni-P coating. The diameter of sample increases by only 3% after plated. The linear coefficient of thermal expansion (CTE) of the substrate is decreased from 16 ppm/K to as low as 12.68 ppm/K with a reduction rate of 20.72%. At 613 K, Ni-P coating crystallizes with a volume shrinkage which partly counteracts the thermal expansion of the substrate and then induces a small CTE, which is named crystallization compensation mechanism. After crystallization, a diffusion layer composed mainly of FeNi3, one of the primary phases of NiFe Invar alloys, generates in-situ at the interface of coating and substrate. This diffusion layer plays a key role in inhibiting the thermal expansion of iron substrate, which is named diffusion-layer inhibitory mechanism. These findings are, in principle, applicable to all the ferrous alloys so that a potential easy way can be promoted to decrease the CTEs of ferrous alloys.
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