The fast and direct characterization of blue-and-white porcelain glaze from Jingdezhen by laser ablation-inductively coupled plasma mass spectrometry

The fast and direct characterization of blue-and-white porcelain glaze from Jingdezhen by laser ablation-inductively coupled plasma mass spectrometry
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激光烧蚀-电感耦合等离子体质谱法快速直接表征景德镇青花瓷釉

DOI:
10.1039/c5ay00875a
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发表时间:
2015-06
期刊:
影响因子:
3.1
通讯作者:
Chen Kaiyun
Chen Kaiyun
中科院分区:
化学3区
文献类型:
--
作者:
Bao Zhian;Yuan Honglin;Wen Rui;Chen Kaiyun

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利用激光烧蚀-电感耦合等离子体质谱(LA-ICP-MS)技术对明代景德镇青花白色瓷进行了元素分析,并对青花瓷进行了分类。根据铁锰钴分布和钴含量,将明代白色瓷分为洪武、宣德、万历三个时期,分别代表明初、明中、晚三个时期。提出以铁锰比和浅蓝区钴含量作为景德镇白色瓷分类的依据。HW、XD和WL的Fe/Mn参考值分别为11.9 ± 0.39、2.31 ± 0.54和7.09 ± 2.07 μg g−1,而HW、XD和WL瓷的钴浓度分别为2500 μg g−1。其它元素如Li、B、Mn、Ni、Cr、Ho、Pb、Th、U和稀土元素也可辅助白色瓷的分类。需要对更多的青花白色瓷样品进行LA-ICP-MS分析,以获得更多的元素浓度,并建立青花白色瓷鉴别的统计数据库。
This study evaluated the classification of blue-and-white porcelains of Jingdezhen during the Ming Dynasties based on elemental concentrations measured by laser ablation-inductively coupled plasma mass spectrometry (LA-ICP-MS). The blue-and-white porcelains of the Ming Dynasties are subdivided into three periods: Hongwu (HW), Xuande (XD) and Wanli (WL), representing the early Ming, middle Ming and late Ming Dynasties, according to Fe–Mn–Co distribution and Co content. We propose Fe/Mn ratio and Co content in the light-blue areas as criteria for the classification of blue-and-white porcelains of Jingdezhen. The reference values for Fe/Mn of HW, XD and WL are 11.9 ± 0.39, 2.31 ± 0.54, and 7.09 ± 2.07 μg g−1, while the cobalt concentrations of HW, XD and WL porcelains are 2500 μg g−1, respectively. Other elements including Li, B, Mn, Ni, Cr, Ho, Pb, Th, U and rare earth elements can also assist in the classification of the blue-and-white porcelain. Further measurements of more blue-and-white porcelains need to be analyzed using LA-ICP-MS to get more elemental concentrations and create a statistical database for blue-and-white porcelain identification.
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