Luminescent Gold Nanoparticles with Mixed Valence States Generated from Dissociation of Polymeric Au (I) Thiolates.
Luminescent Gold Nanoparticles with Mixed Valence States Generated from Dissociation of Polymeric Au (I) Thiolates.
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DOI：
10.1021/jp9122584
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发表时间：
2010
期刊：
影响因子：
--
通讯作者：
Zheng J
中科院分区：
文献类型：
--
作者：
Zhou C;Sun C;Yu M;Qin Y;Wang J;Kim M;Zheng J
Dissociation process of glutathione-gold(I) polymers in aqueous solution resulted in the formation of a class of ~2 nm gold nanoparticles. Different from the same sized but NaBH4 reduced gold nanoparticles, these nanoparticles exhibit strong luminescence but no surface plasmon absorption. Luminescence lifetimes of the nanoparticles were found strongly dependent on excitation wavelengths, and singlet and triplet excited states involving the emission were found degenerate in energy. X-ray photoelectron spectroscopic studies showed that nearly 40~50% gold atoms in the luminescent nanoparticles were in gold(I) state, which are responsible for the unique optical properties of the luminescent gold nanoparticles. These luminescent nanoparticles can be considered an intermediate state between luminescent gold(I) complexes and reduced nonluminescent gold nanoparticles.
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