Dibenzothiophene-S,S-dioxide derivatives containing triphenylamine and tetraphenylethene: Synthesis, aggregation-induced emission and electroluminescence

Dibenzothiophene-S,S-dioxide derivatives containing triphenylamine and tetraphenylethene: Synthesis, aggregation-induced emission and electroluminescence
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含有三苯胺和四苯乙烯的二苯并噻吩-S,S-二氧化物衍生物:合成、聚集诱导发射和电致发光

DOI:
10.1016/j.dyepig.2020.108526
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发表时间:
2020-09
期刊:
影响因子:
4.5
通讯作者:
Ma Dongge
Ma Dongge
中科院分区:
材料科学2区
文献类型:
--
作者:
Liang Aihui;Hu Sifan;Wang Zhiping;Zhou Wenjing;Xu Jiarong;Cai Mingzhong;Ma Dongge

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Several well-defined donor-acceptor (D-A) dibenzothiophene-S,S-dioxide (SO) derivatives possessing aggregation-induced emission (AIE) behaviour decorated by tetraphenylethene (TPE) and triphenylamine (TPA) were synthesized and characterized. The photophysical, thermal, electrochemical and electroluminescent (EL) properties, as well as the AIE property of the luminogens were discussed. All the luminogens show high thermal stability and exhibit good photoluminescence, and exhibit atypical AIE characteristic. Among the three OLEDs, the device of TPA–FSO–TPA showed the best performances with aVonof 4.0 V, LEmaxof 10.05 cd A−1, EQEmaxof 3.8% andLmaxof 14,670 cd m−2. Upon change of the operating voltage, the electroluminescent (EL) spectra of the devices based on TPA–FSO–TPA, TPA–FSO–TPE and TPE–FSO–TPE show negligible shift, indicating good device stability could be achieved in this system.
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