Synthesis of hydroxylated azacalix[1]arene[3]pyridines from hydrolysis of high valent arylcopper complexes and conversion to a double azacalix[1]arene[3]pyridine host molecule
Synthesis of hydroxylated azacalix[1]arene[3]pyridines from hydrolysis of high valent arylcopper complexes and conversion to a double azacalix[1]arene[3]pyridine host molecule
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通过水解高价芳基铜络合物合成羟基化氮杂花[1]芳烃[3]吡啶并转化为双氮杂花[1]芳烃[3]吡啶主体分子
DOI：
10.1039/c6qo00669h
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发表时间：
2017-02
期刊：
影响因子：
--
通讯作者：
Mei-Xiang Wang
中科院分区：
文献类型：
--
作者：
Qian Zhang;Mei-Xiang Wang
Hydrolysis of shelf-stable and structurally well-defined arylcopper(II) and arylcopper(III) complexes was investigated. Under alkali conditions all arylcopper(II) compounds underwent efficient hydrolysis at ambient temperature to produce exclusively lower-rim-hydroxylated azacalix[1]arene[3]pyridines in excellent yields. The identical products were obtained in only moderate yields from the same hydrolytic reaction of arylcopper(III) compounds. The latter reaction also yielded a 4,4′-biphenol-joint double azacalix[1]arene[3]pyridine product. The double azacalix[1]phenol[3]pyridine was then prepared in good yield from the CuCl2/TMEDA-catalyzed oxidative homocoupling of two azacalix[1]phenol[3]pyridines. The supramolecular application of the resulting double azacalixaromatics was demonstrated by their complexation with aliphatic diamines to form one-dimensional molecular assemblies in the solid state.
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用于高效液相色谱的新型氧桥杯[2]芳烃[2]三嗪固定相。
DOI：
10.1016/j.chroma.2011.12.031
发表时间：
2012-02
期刊：
Journal of chromatography. A
影响因子：
--
作者：
通讯作者：
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影响因子：
1.8
作者：
Claudia Gargiulli;G. Gattuso;A. Notti;S. Pappalardo;M. F. Parisi;F. Puntoriero
通讯作者：
Claudia Gargiulli;G. Gattuso;A. Notti;S. Pappalardo;M. F. Parisi;F. Puntoriero
影响因子：
3.1
作者：
H. Tsue;Hiroki Takahashi;Koichi Ishibashi;Rikako Inoue;S. Shimizu;D. Takahashi;R. Tamura
通讯作者：
H. Tsue;Hiroki Takahashi;Koichi Ishibashi;Rikako Inoue;S. Shimizu;D. Takahashi;R. Tamura
影响因子：
4.9
作者：
Zu‐Li Wang;Liang Zhao;Mei-Xiang Wang
通讯作者：
Zu‐Li Wang;Liang Zhao;Mei-Xiang Wang
甲基氮杂花吡啶：具有独特识别特性的显着桥接氮调节构象和空腔
影响因子：
4.3
作者：
Gong, Han-Yuan;Zhang, Xiao-Hang;Wang, Mei-Xiang
通讯作者：
Wang, Mei-Xiang