Shining Light on Porous Liquids: From Fundamentals to Syntheses, Applications and Future Challenges

Shining Light on Porous Liquids: From Fundamentals to Syntheses, Applications and Future Challenges
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照亮多孔液体:从基础到合成、应用和未来挑战

DOI:
10.1002/adfm.202104162
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发表时间:
2021-09
影响因子:
19
通讯作者:
Yaping Zheng
Yaping Zheng
中科院分区:
材料科学1区
文献类型:
--
作者:
Dechao Wang;Yangyang Xin;Dongdong Yao;Xiaoqian Li;Hailong Ning;Hongmin Zhang;Yudeng Wang;Xiaoqian Ju;Zhongjie He;Zhiyuan Yang;Wendi Fan;Peipei Li;Yaping Zheng

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多孔液体(PLs)是一种新兴的流动液体材料,结合了多孔固体和流动液体的优点,自2007年提出PLs概念以来,它受到了广泛的关注。同时,特别是自2017年以来,PLs在多功能合成策略和新兴应用方面取得了越来越大的成功。由于缺乏及时的全面综述,因此迅速总结和全面理解无疑是刻不容缓的。因此,这篇批判性评论全面总结了 PL 的基础化学、发展历史、合成策略和新兴应用的进展。首先,回顾了基础化学和发展历史。然后,重点介绍了 PL 的合成策略。此外,还回顾了纯理论模拟的横切研究。同时,还分析了 PL 令人畏惧的表征问题。接下来,详细回顾 PL 应用的最新技术。最后,提出了有关 PL 的剩余挑战和未来方向的观点。据推测,这种对 PL 的批判性综合审查可以激励科学界关注各种应用的特定任务材料,例如气体吸附、膜分离、催化转化、手性分离、热管理和电解质等。
Porous liquids (PLs), an emerging type of flowing liquid materials that combine the merits of porous solids and flowing liquids, have garnered immense attention since the concept of PLs was proposed in 2007. Meanwhile, PLs have witnessed growing success in versatile synthesis strategies and emerging applications, especially since 2017. Given the lack of a timely comprehensive review, developing a prompt summary with a comprehensive understanding is undoubtedly urgent. Thus, this critical review offers a comprehensive summary of the progress in fundamental chemistry, developmental history, synthetic strategies, and emerging applications of PLs. First, the fundamental chemistry and developmental history are reviewed. Then, the synthesis strategies of PLs are highlighted. Additionally, crosscutting studies of pure theoretical simulations are reviewed. Meanwhile, the daunting characterization issues of PLs are analyzed. Next, the state‐of‐the‐art of PLs applications is reviewed in detail. In the end, perspectives regarding the remaining challenges and future directions for PLs are presented. It is speculated that this critical comprehensive review of PLs could inspire scientific communities who focus on the task‐specific materials for various applications, such as gas sorption, membrane separation, catalytic conversion, chiral separation, thermal management and electrolyte, and so on.
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