M≡E and M=E Complexes of Iron and Cobalt that Emphasize Three-fold Symmetry (E = O, N, NR).

M≡E and M=E Complexes of Iron and Cobalt that Emphasize Three-fold Symmetry (E = O, N, NR).
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DOI:
10.1016/j.ccr.2011.01.009
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发表时间:
2011-04
影响因子:
20.6
通讯作者:
Peters JC
Peters JC
中科院分区:
化学1区
文献类型:
--
作者:
Saouma CT;Peters JC

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中晚期过渡金属配合物具有末端多键配体,如氧基、亚胺和氮化物,已被用作几种具有合成和生物意义的催化转化的中间体。直到大约十年前,这种物种的独立例子几乎是未知的。在过去十年左右的时间里,已经发现了许多化学上定义明确的这类物种的例子。在此背景下,本文综述了局部三重对称条件下四坐标和五坐标Fe(E)和Co(E)的发展。
Mid-to-late transition metal complexes that feature terminal, multiply bonded ligands such as oxos, imides, and nitrides have been invoked as intermediates in several catalytic transformations of synthetic and biological significance. Until about ten years ago, isolable examples of such species were virtually unknown. Over the past decade or so, numerous chemically well-defined examples of such species have been discovered. In this context, the presentreview summarizes the development of 4- and 5-coordinate Fe(E) and Co(E) species under local three-fold symmetry.
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