Revitalized interest in vanadium pentoxide as cathode material for lithium-ion batteries and beyond
Revitalized interest in vanadium pentoxide as cathode material for lithium-ion batteries and beyond
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重燃人们对五氧化二钒作为锂离子电池及其他电池阴极材料的兴趣
DOI：
10.1016/j.ensm.2017.10.014
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发表时间：
2018-03
影响因子：
20.4
通讯作者：
Guozhong Cao
中科院分区：
文献类型：
--
作者：
Jinhuan Yao;Yanwei Li;Robert C. Massé;Evan Uchaker;Guozhong Cao
对五氧化二钒（V2O5）的重新关注源于可充电电池的两个非常重要的发展。一个是推动锂离子电池向更高能量密度的方向发展：使用金属锂作为阳极，寻找更高容量和更高电压的阴极。金属锂负极的使用消除了V2O5正极不含锂离子的一大障碍。V2O5在已知的阴极材料中具有最高的可逆容量。另一个是最近对锂离子电池（LIB）以外的阴极材料的深入研究。在过去的几年里，对互补碱离子电池技术的兴趣已经出现了巨大的复苏。在一系列替代化学物质中，V2 O5作为钠离子电池（NIB）、镁离子电池（MIB）和其他金属电池的阴极取得了最可观和最有前途的进展。与LIB不同，这些系统面临着一系列新的挑战，这些挑战由传输的离子种类的性质和对电极材料的影响决定。本文综述了V2O5正极材料在金属电池领域中的最有趣或最令人惊讶的现象，提出的重要问题以及下一步的实验和理论步骤。本文综述了表面化学、结晶度、掺杂、缺陷和纳米结构对锂离子嵌入性能的影响以及其他金属电池包括NIBs和MIBs的最新进展。讨论了V_2O_5基正极材料的发展前景和面临的挑战。
Revitalized interest in vanadium pentoxide (V2O5) arises from two very important developments in rechargeable batteries. One is the push on lithium-ion batteries for higher energy density batteries: using lithium metal as anode and searching for higher capacity and high voltage cathode. Using lithium metal anode eliminates the big obstacle for V2O5 cathode that does not come with lithium ions. V2O5 possesses the highest reversible capacity among known cathode materials. Another is the recent intensive research for cathode materials beyond Li-ion batteries (LIBs). In the past several years, interest in complementary alkali-ion battery technologies has seen a tremendous resurgence. Out of the set of alternative chemistries, V2O5 has seen the most considerable and promising gains as a cathode for Na-ion battery (NIB), Mg-ion battery (MIB), and other metal batteries. Unlike LIBs, these systems face a set of new challenges as dictated by the properties of the transported ionic species and the consequent effects on the electrode materials. The purpose of this review is to summarize the most interesting or surprising phenomena, the important questions raised and next experimental and theoretical steps to advance V2O5 cathode materials in the field of metal batteries. This review focused on selected topics covering the influences of surface chemistry, crystallinity, doping, defects, and nanostructures on the lithium-ion intercalation properties and recent developments on other metal batteries including NIBs and MIBs. The perspectives and remaining challenges for V2O5 based cathode materials have been discussed.
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影响因子：
15
作者：
H. Willard;G. Smith
通讯作者：
H. Willard;G. Smith
影响因子：
2.5
作者：
J. Livage;O. Pelletier;P. Davidson
通讯作者：
J. Livage;O. Pelletier;P. Davidson
DOI：
10.1016/0021-9797(84)90173-5
发表时间：
1984-04
期刊：
--
影响因子：
--
作者：
P. Aldebert;Hans‐W. Haesslin;N. Baffier;J. Livage
通讯作者：
P. Aldebert;Hans‐W. Haesslin;N. Baffier;J. Livage
影响因子：
8.6
作者：
Y. C. and;Q. Qin
通讯作者：
Y. C. and;Q. Qin
影响因子：
5.4
作者：
H. Oliveira;Carlos Frederico de Oliveira Graeff;J. M. Rosolen
通讯作者：
H. Oliveira;Carlos Frederico de Oliveira Graeff;J. M. Rosolen