Synthesis of double-shelled copper chalcogenide hollow nanocages as efficient counter electrodes for quantum dot-sensitized solar cells

Synthesis of double-shelled copper chalcogenide hollow nanocages as efficient counter electrodes for quantum dot-sensitized solar cells
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双壳铜硫族化物空心纳米笼的合成作为量子点敏化太阳能电池的有效对电极

DOI:
10.1016/j.mtener.2017.07.015
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发表时间:
2017-09
影响因子:
9.3
通讯作者:
Xu Jun
Xu Jun
中科院分区:
材料科学3区
文献类型:
--
作者:
Hu Zhengqiao;Zhou Ru;Sun Weijun;Zhang Junjun;Lee Chun-Sing;Xu Jun

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Double-shelled copper chalcogenide (Cu2−xSe and Cu7S4) nanocages of about 250 nm sizes are synthesized respectively by using Cu2O nanocubes as sacrificial precursor via Kirkendall diffusion and etching. Both the double-shelled Cu2−xSe and Cu7S4nanocages are demonstrated to be excellent counter electrode (CE) materials in quantum dot-sensitized solar cells (QDSSCs) and exhibit high electrocatalytic activities for polysulfide electrolyte regeneration. The QDSSCs using the double-shelled Cu2−xSe and Cu7S4nanocages as CEs show power conversion efficiencies (PECs) of 4.76 and 4.53%, respectively, which are 19.6% and 15.3% higher than the corresponding devices using the single-shelled Cu2−xSe and Cu7S4nanocages as CEs. The overall enhancement of photovoltaic performance including the fill factor, short-circuit current density and PEC is attributed to the larger CE-electrolyte interface provided by the double-shelled nanocages facilitating fast electron transfer in the QDSSCs.
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