Synthesis of double-shelled copper chalcogenide hollow nanocages as efficient counter electrodes for quantum dot-sensitized solar cells
Synthesis of double-shelled copper chalcogenide hollow nanocages as efficient counter electrodes for quantum dot-sensitized solar cells
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双壳铜硫族化物空心纳米笼的合成作为量子点敏化太阳能电池的有效对电极
DOI:
10.1016/j.mtener.2017.07.015
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发表时间:
2017-09
影响因子:
9.3
通讯作者:
Xu Jun
中科院分区:
文献类型:
--
作者:
Hu Zhengqiao;Zhou Ru;Sun Weijun;Zhang Junjun;Lee Chun-Sing;Xu Jun
Double-shelled copper chalcogenide (Cu2−xSe and Cu7S4) nanocages of about 250 nm sizes are synthesized respectively by using Cu2O nanocubes as sacrificial precursor via Kirkendall diffusion and etching. Both the double-shelled Cu2−xSe and Cu7S4nanocages are demonstrated to be excellent counter electrode (CE) materials in quantum dot-sensitized solar cells (QDSSCs) and exhibit high electrocatalytic activities for polysulfide electrolyte regeneration. The QDSSCs using the double-shelled Cu2−xSe and Cu7S4nanocages as CEs show power conversion efficiencies (PECs) of 4.76 and 4.53%, respectively, which are 19.6% and 15.3% higher than the corresponding devices using the single-shelled Cu2−xSe and Cu7S4nanocages as CEs. The overall enhancement of photovoltaic performance including the fill factor, short-circuit current density and PEC is attributed to the larger CE-electrolyte interface provided by the double-shelled nanocages facilitating fast electron transfer in the QDSSCs.
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影响因子:
4.9
作者:
Cao, Hongliang;Qian, Xuefeng;Zhu, Zikang
通讯作者:
Zhu, Zikang
DOI:
10.1039/c3cp44485f
发表时间:
2013-03
期刊:
Physical chemistry chemical physics : PCCP
影响因子:
--
作者:
Yufeng Liu;Yian Xie;Houlei Cui;Wei Zhao;Chongyin Yang;Yaoming Wang;Fuqiang Huang;N. Dai
通讯作者:
Yufeng Liu;Yian Xie;Houlei Cui;Wei Zhao;Chongyin Yang;Yaoming Wang;Fuqiang Huang;N. Dai
影响因子:
4.9
作者:
Zusing Yang;Chia-Ying Chen;Prathik Roy;Huan‐Tsung Chang
通讯作者:
Zusing Yang;Chia-Ying Chen;Prathik Roy;Huan‐Tsung Chang
影响因子:
41.2
作者:
Luther, Joseph M.;Jain, Prashant K.;Alivisatos, A. Paul
通讯作者:
Alivisatos, A. Paul
影响因子:
15
作者:
Dorfs, Dirk;Haertling, Thomas;Manna, Liberato
通讯作者:
Manna, Liberato