Additive Manufacturing of Transparent Multi-Component Nanoporous Glasses.
Additive Manufacturing of Transparent Multi-Component Nanoporous Glasses.
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DOI：
10.1002/advs.202305775
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发表时间：
2023-12
期刊：
影响因子：
15.1
通讯作者：
He, Jin
中科院分区：
文献类型：
--
作者：
Li, Beining;Li, Zhenjiang;Cooperstein, Ido;Shan, Wenze;Wang, Shuaipeng;Jiang, Benxue;Zhang, Long;Magdassi, Shlomo;He, Jin
关键词：
Fabrication of glass with complex geocd the low resolution of particle‐based or fused glass technologies. Herein, a high‐resolution 3D printing of transparent nanoporous glass is presented, by the combination of transparent photo‐curable sol–gel printing compositions and digital light processing (DLP) technology. Multi‐component glass, including binary (Al2O3‐SiO2), ternary (ZnO‐Al2O3‐SiO2, TiO2‐Al2O3‐SiO2), and quaternary oxide (CaO‐P2O5‐Al2O3‐SiO2) nanoporous glass objects with complex shapes, high spatial resolutions, and multi‐oxide chemical compositions are fabricated, by DLP printing and subsequent sintering process. The uniform nanopores of Al2O3‐SiO2‐based nanoporous glasses with the diameter (≈6.04 nm), which is much smaller than the visible light wavelength, result in high transmittance (>95%) at the visible range. The high surface area of printed glass objectives allows post‐functionalization via the adsorption of functional guest molecules. The photoluminescence and hydrophobic modification of 3D printed glass objectives are successfully demonstrated. This work extends the scope of 3D printing to transparent nanoporous glasses with complex geometry and facile functionalization, making them available for a wide range of applications. This work reports metal chelates sol–gel route to 3D print complex‐shaped macroscopic transparent glass structures with inherent porosity and broad compositional design space. This method extends the transparent glass additive manufacturing technology from classical dense glass to the field of nanoporous multi‐component glass, bearing significant promise for their utilization in broad applications, including in light‐emitting devices and sensors.
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