Chemical analysis of white porcelains from the Ding Kiln site, Hebei Province, China

Chemical analysis of white porcelains from the Ding Kiln site, Hebei Province, China
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中国河北省定窑遗址白瓷的化学分析

DOI:
10.1016/j.jas.2011.07.026
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发表时间:
2012-04
影响因子:
2.8
通讯作者:
Jianfeng Cui, Nigel Wood, Dashu Qin
Jianfeng Cui, Nigel Wood, Dashu Qin
中科院分区:
地球科学2区
文献类型:
--
作者:
Jianfeng Cui, Nigel Wood, Dashu Qin

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定窑是中世纪中国最著名的早期窑,生产了大量的白色和乳白色白色瓷器,具有杰出的技术和美学品质。自1949年以来,它们分别于1965年、1987年和2009年被挖掘了三次。在这项最新的研究中,使用激光烧蚀技术(ICP-AES)分析了69个来自确定环境和2009年挖掘的白色瓷器碎片。这些样品分别来自五代、北方和金代(公元10世纪初至13世纪初)。结果表明,不同时期的定窑器表现出不同的特征,这些特征可以通过化学成分来体现。在生产的早期阶段,定窑主体主要由高烧高岭土组成,主要是钙质材料作为熔剂。北方宋以后,部分钙质物质被更富钾质的物质所取代。釉的组成与坯体的组成有平行的演变过程。然而,由于釉料中的二氧化钛含量很低,似乎不太可能在釉料配方中使用主体的主要粘土成分。在窑址历史的大部分时间里,釉似乎主要是由与用于制作定窑瓷器的主体粘土相同的富含硅质助熔剂的材料制成的,再加上一些额外的钙质材料。釉中的P2 O 5含量表明,木灰可能是釉配方中CaO的来源之一。
The Ding kilns were some of the most famous early kilns of medieval China, producing huge quantities of white and cream-white porcelains of outstanding technical and aesthetic quality. Since 1949 they have been excavated three times, in 1965, in 1987, and in 2009 respectively. In this latest study 69 white porcelain sherds from assured contexts and from the 2009 excavations were analyzed using laser ablation techniques (ICP-AES). The samples date from Five Dynasties, Northern Song and Jin Dynasties respectively (early 10thto early 13thC CE). The results show that Ding wares of different times show different characteristics that can be demonstrated through chemical composition. During the early phase of production the Ding ware bodies consisted largely of high firing kaolinitic clays with predominantly calcareous materials as fluxes. After the early Northern Song Dynasty, some calcareous material was replaced by a more potassic material. The compositions of the glazes show a parallel evolution to the bodies. However, because the glazes are very low in titania it seems unlikely that the main clay ingredients of the bodies could have been used in the glaze recipes. For much of the kiln site’s history the glazes appear to have been made mainly from the same siliceous flux-rich materials that had been blended with the main body-clays used to make the Ding ware porcelains, plus some extra calcareous material. The P2O5contents of the glazes suggest that wood ash may have been one source of CaO in the glaze recipes.
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发表时间: 1972
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