Rare Alkali Elements as Markers of Local Glass Working in Medieval Tolmo de Minateda (Spain).

Rare Alkali Elements as Markers of Local Glass Working in Medieval Tolmo de Minateda (Spain).
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DOI:
10.1002/cplu.202200147
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发表时间:
2022-09
期刊:
影响因子:
3.4
通讯作者:
Gutierrez Lloret, Sonia
Gutierrez Lloret, Sonia
中科院分区:
化学3区
文献类型:
--
作者:
Schibille, Nadine;Amoros Ruiz, Victoria;De Juan Ares, Jorge;Gutierrez Lloret, Sonia

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罗马和早期伊斯兰玻璃的分析数据建立了几个与黎凡特和埃及的玻璃制造中心有关的主要玻璃生产集团。相比之下,二级玻璃作坊的活动在第一个千年玻璃的成分指纹中基本上是看不见的。激光烧蚀电感耦合等离子体质谱(LA-ICP-MS)分析了261个来自西哥特人定居点Tolmo de Minateda(西班牙)的玻璃,发现了由于二次玻璃加工和回收而导致的特定地点的污染模式,即稀有碱金属元素(Li,K,Rb,Cs)的独特组合对玻璃批料的富集。Li的中位数为21 ppm,特别与众不同。高锂含量(Li>30 ppm)也是伊斯兰时期伊比利亚植物灰玻璃的特征之一。 已知最早的这种类型玻璃的例子是在托尔莫发现的世纪遗迹中。 稀有碱元素污染的中世纪玻璃质材料的坩埚陶瓷和燃料蒸汽显示在这项工作中。系统地回收旧碎玻璃,使用由伊比利亚中部地块的粘土制成的坩埚,产生了独特的微量元素模式,可以作为伊比利亚玻璃加工的标识符。
Analytical data of Roman and early Islamic glass established several primary glass production groups linked to glassmaking centres in the Levant and in Egypt. In contrast, the activities of secondary glass workshops are largely invisible in the compositional fingerprint of first millennium glass. Laser ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS) of 261 glass finds from the Visigothic settlement of Tolmo de Minateda (Spain) revealed a site‐specific contamination pattern due to secondary glass processing and recycling, namely the enrichment of the glass batch by a unique combination of rare alkali elements (Li, K, Rb, Cs). With a median of 21 ppm, Li is particularly distinctive. Elevated lithium contents (Li>30 ppm) are also one of the characteristic features of Iberian plant ash glass from the Islamic period. The earliest known examples of this type of glass were found among the ninth‐century remains from Tolmo. Rare alkali element contamination of medieval vitreous materials by both the crucible ceramic and fuel vapour are shown in this work. Systematic recycling of old cullet, using crucibles made from clay from the Central Iberian Massif, resulted in unique trace element patterns that can serve as identifiers of Iberian glass processing.
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