Real-time monitoring of surface-initiated atom transfer radical polymerization using silicon photonic microring resonators: implications for combinatorial screening of polymer brush growth conditions.
Real-time monitoring of surface-initiated atom transfer radical polymerization using silicon photonic microring resonators: implications for combinatorial screening of polymer brush growth conditions.
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使用硅光子微环谐振器实时监测表面引发的原子转移自由基聚合:对聚合物刷生长条件的组合筛选的影响。
DOI:
10.1021/ja205358g
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发表时间:
2011-09-28
影响因子:
15
通讯作者:
Bailey, Ryan C.
中科院分区:
文献类型:
--
作者:
Limpoco, F. Ted;Bailey, Ryan C.
We directly monitor in parallel and in real-time the temporal profiles of polymer brushes simultaneously grown via multiple ATRP reaction conditions on a single substrate using arrays of silicon photonic microring resonators. In addition to probing relative polymerization rates, we also show the ability to evaluate the dynamic properties of the in situ grown polymers. Taken together, this presents a powerful new platform for studying modified interfaces that may allow for the combinatorial optimization of surface initiated polymerization conditions.
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