The open, the closed, and the empty: time-resolved fluorescence spectroscopy and computational analysis of RC-LH1 complexes from Rhodopseudomonas palustris.
The open, the closed, and the empty: time-resolved fluorescence spectroscopy and computational analysis of RC-LH1 complexes from Rhodopseudomonas palustris.
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开放、封闭和空:沼泽红假单胞菌 RC-LH1 复合物的时间分辨荧光光谱和计算分析。
DOI:
10.1021/jp510822k
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发表时间:
2015
期刊:
影响因子:
--
通讯作者:
Beyer SR
中科院分区:
文献类型:
--
作者:
Beyer SR
We studied the time-resolved fluorescence of isolated RC-LH1 complexes fromRhodopseudomonas palustrisas a function of the photon fluence and the repetition rate of the excitation laser. Both parameters were varied systematically over 3 orders of magnitude. On the basis of a microstate description we developed a quantitative model for RC-LH1 and obtained very good agreement between experiments and elaborate simulations based on a global master equation approach. The model allows us to predict the relative population of RC-LH1 complexes with the special pair in the neutral state or in the oxidized state P+and those complexes that lack a reaction center.
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