A novel biological active multilayer film based on polyoxometalate with pendant support-ligand
A novel biological active multilayer film based on polyoxometalate with pendant support-ligand
复制标题
基于带有悬垂支持配体的多金属氧酸盐的新型生物活性多层膜
DOI:
10.1016/j.jssc.2005.09.031
复制
发表时间:
2005-12
影响因子:
3.3
通讯作者:
Baoxia Dong
中科院分区:
文献类型:
--
作者:
Huiyuan Ma;Jun Peng;* Zhangang Han;Xia Yu;Baoxia Dong
A novel nanosized biological active multilayer film composed of polyoxometalate (POM) anion α-[SiW11O39Co(H2PO4)]7−(abbr. SiW11Co–PO4) and poly(diallyldi methylammonium chloride) (abbr. PDDA) was fabricated by layer-by-layer self-assembly (LBL). The composition and growth processes of the films have been determined by X-ray photoelectron spectra (XPS) and ultraviolet-visible absorption spectra (UV). The composite film was formed by the alternate adsorption of SiW11Co–PO4and PDDA, and the deposition process was quantitative and highly reproducible from layer to layer. The morphology of the film was studied by atomic force microscopy (AFM), which showed that the film was relatively uniform and smooth, and POM anions aggregated into nanoclusters distributing on the surface uniformly. The film exhibited favorable electrochemical behavior of POM indicated by cyclic voltammetry (CV). The film can immobilize the DNA molecules via Mg2+-bridging medium.
登录
查看更多内容
影响因子:
3.9
作者:
Y. Okahata;K. Ijiro;Y. Matsuzaki
通讯作者:
Y. Okahata;K. Ijiro;Y. Matsuzaki
影响因子:
29.4
作者:
C. Schmitz;M. Thelakkat;H. Schmidt
通讯作者:
C. Schmitz;M. Thelakkat;H. Schmidt
影响因子:
4
作者:
Jun Peng;Huiyuan Ma;Zhan-gang Han;Bao-xia Dong;Wenzhu Li;Jun Lu;E. Wang
通讯作者:
Jun Peng;Huiyuan Ma;Zhan-gang Han;Bao-xia Dong;Wenzhu Li;Jun Lu;E. Wang
影响因子:
8.6
作者:
Kim, HN;Keller, SW;Decher, G
通讯作者:
Decher, G
影响因子:
15
作者:
Thompson, LA;Kowalik, J;Janata, J
通讯作者:
Janata, J