Detecting Water Constituents Unique to Septic Tanks as a Wastewater Source in the Environment by Nontarget Analysis: South Florida's Deering Estate Rehydration Project Case Study
Detecting Water Constituents Unique to Septic Tanks as a Wastewater Source in the Environment by Nontarget Analysis: South Florida's Deering Estate Rehydration Project Case Study
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通过非目标分析检测作为环境中废水源的化粪池特有的水成分：南佛罗里达州迪林庄园补水项目案例研究
DOI：
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发表时间：
2022
影响因子：
4.1
通讯作者：
P. Gardinali
中科院分区：
文献类型：
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作者：
Kassidy Troxell;Brian Ng;Ingrid M Zamora;P. Gardinali
本研究使用Compound Discoverer Ver 3.1生成了一个基于非目标分析（NTA）的工作流程，以表征在南佛罗里达（美国）的水样中鉴定出的一组来源区分化合物，特别是那些描述淡水环境（Everglades为基础）、城市受影响地区（化化池驱动）和棕榈湾村Charles Deering地产及其周围的沿海（比斯坎湾）终端成员的化合物。对来自互联管理运河系统的水进行了评估，以评估局部排放的影响。由于石灰石为主的地质和运河系统提供了相对畅通的连接通道，化粪池污水的现场处理能力下降，影响了佛罗里达州东南部许多环境中的水。通过高分辨率质谱法和统计分析相结合，确定了一组示踪剂和指示剂（壬二酸、癸烯酮、galaxolidone、甲基紫、单油酸、美托洛尔和1硬脂酰甘油）。初步确定的化合物通常被分配到不同的类别，如染料、个人护理产品和药品。NTA Compound Discoverer Ver 3.1化合物数据（以主成分分析和Kendrick质量缺陷图的形式呈现）显示了废水影响位点和非废水影响位点之间的明显差异，以及在每个位点发现的“Top10”化合物的排名。我们还利用三氯蔗糖对来自不同地点的水进行了比较，以进一步向国家运输管理局提供信息。受脓毒症影响最大的地区三氯蔗糖浓度为3594±94 ng/L，随后呈下降趋势，比斯坎湾的三氯蔗糖浓度最低为122±94 ng/L。三氯蔗糖浓度进一步证明了化粪池对该系统的影响。三氯蔗糖被确定为淡水和沿海来源之间的保守示踪剂，并且与NTA确定的化粪池流出物的其他可能的独特示踪剂互补。环境科学学报（自然科学版）；2009;31(1):391 - 391。©2022 setac
The present study has generated a workflow based on nontarget analysis (NTA) with Compound Discoverer Ver 3.1 to characterize a set of source‐discriminating compounds identified in water samples from locations in South Florida (USA), particularly those describing a freshwater environment (Everglades based), urban impacted areas (septic tank driven), and coastal (Biscayne Bay) endmembers in and around the Charles Deering Estate property in the Village of Palmetto Bay. Waters from an interconnected managed canal system were assessed to evaluate the influence of localized emissions. Septic tank effluents influence the water in many Southeast Florida environments due to their diminished onsite treatment capacity based on the limestone‐dominated geology and canal systems providing a relatively unobstructed connection pathway. Through a combination of high‐resolution mass spectrometry and statistical analyses, a set of tracers and indicators was determined (azelaic acid, decanophenone, galaxolidone, methyl violet, monoolein, metoprolol, and 1‐stearoylglycerol). Tentatively identified compounds were generally assigned to various categories such as dyes, personal care products, and pharmaceuticals. The NTA Compound Discoverer Ver 3.1 compound data (presented as principal component analysis and Kendrick mass defect plots) showed apparent differences between wastewater‐influenced sites and non–wastewater‐influenced sites along with the ranked “Top10” compounds found at each location. Waters from different locations were also compared using the presence of sucralose to further inform the NTA. The most septic‐influenced site contained 3594 ± 94 ng/L of sucralose with concentrations declining steadily and reaching the lowest concentrations in Biscayne Bay of 122 ± 94 ng/L. The sucralose concentrations provided further evidence of septic influence on this system. Sucralose was determined to be a conservative tracer between the freshwater and coastal sources and complementary to other probable unique tracers of septic tank effluent identified by the NTA. Environ Toxicol Chem 2022;41:1165–1178. © 2022 SETAC
影响因子：
11.4
作者：
Hollender, Juliane;Schymanski, Emma L.;Ferguson, P. Lee
通讯作者：
Ferguson, P. Lee