Solution concentration-dependent tunable emission in cyclometalated iridium complex bearing perylene diimide (PDI) ligand: From visible to near-infrared emission

Solution concentration-dependent tunable emission in cyclometalated iridium complex bearing perylene diimide (PDI) ligand: From visible to near-infrared emission
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带有苝二酰亚胺 (PDI) 配体的环金属化铱配合物中溶液浓度依赖性可调发射:从可见光到近红外发射

DOI:
10.1016/j.dyepig.2018.03.011
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发表时间:
2018-07
期刊:
影响因子:
4.5
通讯作者:
Wang Yafei
Wang Yafei
中科院分区:
材料科学2区
文献类型:
--
作者:
Shi Junwei;Fan Jiang;Qu Zuoming;Wang Song;Wang Yafei

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To explore the multicolor photoluminescence switching in perylene diimide (PDI) derivatives, a PDI-based iridium complex of (ppy)2IrPDI was prepared and characterized by NMR, MS and elemental analysis. This iridium complex showed clearly concentration-dependent emission spectra in solution, which is generated from different excited states (singlet and triplet), as evidenced by experimental and theoretical methods. Conversely, the iridium complex presented phosphorescent near-infrared emission (∼750 nm) both in neat film and in a solid-state polymethylmethacrylate (PMMA) matrix. This research provides another way to access the radiative emission from triplet states of PDI derivatives, which has an important significance for further understanding the photophysics of the PDI based phosphorescent complex.
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