Electrostatically Enhanced Phosphoric Acids: A Tool in Brønsted Acid Catalysis.
Electrostatically Enhanced Phosphoric Acids: A Tool in Brønsted Acid Catalysis.
复制标题
静电增强磷酸：布朗斯台德酸催化工具。
作者：
Jie Ma;S. Kass
报道了一种新型的磷酸催化剂。这些化合物具有一个或两个带正电的中心，静电激活它们。这在包括Friedel-Crafts和Diels-Alder反应以及开环聚合在内的几种成键转化中得到了说明。观察到相应数量级的速率加速度。
A novel type of phosphoric acid catalyst with enhanced reactivity is reported. These compounds possess one or two positively charged centers which electrostatically activate them. This is illustrated in several bond-forming transformations including Friedel-Crafts and Diels-Alder reactions as well as a ring-opening polymerization. Rate accelerations corresponding to orders of magnitude are observed.
影响因子：
16.6
作者：
Kaupmees, Karl;Tolstoluzhsky, Nikita;Leito, Ivo
通讯作者：
Leito, Ivo
影响因子：
16.6
作者：
Liao, Hsuan-Hung;Chatupheeraphat, Adisak;Rueping, Magnus
通讯作者：
Rueping, Magnus