Transition Metal-Catalyzed Selective Carbon-Carbon Bond Cleavage of Vinylcyclopropanes in Cycloaddition Reactions.
Transition Metal-Catalyzed Selective Carbon-Carbon Bond Cleavage of Vinylcyclopropanes in Cycloaddition Reactions.
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环加成反应中过渡金属催化乙烯基环丙烷的选择性碳—碳键断裂
DOI：
10.1021/acs.chemrev.0c00160
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发表时间：
2021-01-13
期刊：
影响因子：
62.1
通讯作者：
Tang, Weiping
中科院分区：
文献类型：
--
作者：
Wang, Jianhua;Blaszczyk, Stephanie A.;Li, Xiaoxun;Tang, Weiping
综述了过渡金属催化乙烯基环丙烷（VCPs）C-C键断裂的方法和应用，重点介绍了环加成反应和相关加成反应。过渡金属，包括钯、镍、铁、钌、铑、钴和铱，可以催化活化或非活化VCP中C-C键的裂解。此外，这些键断裂反应可以作为分子内或分子间过程发生。在引言中讨论了活化和非活化VCP的性质。各种过渡金属催化的环加成和加成反应，涉及裂解的C-C键在活化的VCPs然后在下一章讨论。过渡金属催化的环加成反应涉及非活化VCP中C-C的裂解，在下面的章节中进行了总结。最后，最后一章概述了挑战和潜在的机会。
In this review, transition metal-catalyzed methodologies and applications that exploit C–C bond cleavage of vinylcyclopropanes (VCPs) are summarized with a focus on cycloaddition and related addition reactions. Transition metals, including palladium, nickel, iron, ruthenium, rhodium, cobalt, and iridium, can catalyze the cleavage of C–C bonds in activated or non-activated VCPs. Additionally, these bond-breaking reactions can occur as intra- or intermolecular processes. The properties of activated and non-activated VCPs are discussed in the introduction. Various transition metal-catalyzed cycloaddition and addition reactions involving the cleavage of C–C bonds in activated VCPs are then discussed in the next chapter. The transition metal-catalyzed cycloadditions involving the cleavage of C–C in non-activated VCPs are summarized in the following chapter. Finally, challenges and potential opportunities are outlined in the last chapter.
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影响因子：
2.1
作者：
Fan, Xiaohui;Zhuo, Lian-Gang;Yu, Zhi-Xiang
通讯作者：
Yu, Zhi-Xiang
影响因子：
5.2
作者：
Gai, Sinan;Lucas, Nigel T.;Hawkins, Bill C.
通讯作者：
Hawkins, Bill C.
影响因子：
4.1
作者：
Huang, Feng;Yao, Zhong-Ke;Yu, Zhi-Xiang
通讯作者：
Yu, Zhi-Xiang
影响因子：
3.6
作者：
Feng, Yu;Yu, Zhi-Xiang
通讯作者：
Yu, Zhi-Xiang
影响因子：
1.8
作者：
BURGESS, K
通讯作者：
BURGESS, K