Investigation of interfacial interaction and structural transition for epoxy/nanotube composites by positron annihilation lifetime spectroscopy

Investigation of interfacial interaction and structural transition for epoxy/nanotube composites by positron annihilation lifetime spectroscopy
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正电子湮没寿命谱研究环氧树脂/纳米管复合材料的界面相互作用和结构转变

DOI:
10.1063/1.3067873
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发表时间:
2009-01
影响因子:
4
通讯作者:
--
中科院分区:
物理与天体物理2区
文献类型:
--
作者:

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Positron annihilation lifetime spectroscopy was employed to study the effect of amine modification on interfacial interaction and structural transition for epoxy/multiwalled carbon nanotube (MWNT) composites. Temperature dependence of orthopositronium lifetimes suggests that sample with amine-modified MWNTs possesses the highest glass transition temperature compared with unmodified samples and neat epoxy resin, which indicates that stronger interfacial interactions exist between epoxy matrix and amine-modified MWNTs, as a result of the covalent bonds and other weak forces. This is testified by interaction parameter β calculated in terms of the positron annihilation parameter.
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