Magnetic nanoparticles encapsulated latexes prepared with photo-initiated miniemulsion polymerization

Magnetic nanoparticles encapsulated latexes prepared with photo-initiated miniemulsion polymerization
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光引发细乳液聚合制备磁性纳米颗粒封装乳胶

DOI:
10.1007/s00396-010-2310-y
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发表时间:
2010-10
影响因子:
2.4
通讯作者:
Gu Junwei
Gu Junwei
中科院分区:
化学4区
文献类型:
--
作者:
Zhang Qiuyu;Jian Liang;Dou Jinbo;Gu Junwei

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这项研究描述了光引发甲基丙烯酸甲酯细乳液聚合和磁性纳米颗粒的引入。以光引发剂为引发剂的水包油型微乳液,紫外光照射15min,反应温度低于45℃,可用于磁性纳米粒子的包埋。激光粒度仪测量的颗粒大小分布较窄。用透射电子显微镜和扫描电子显微镜对粒子的形貌进行了观察。利用X射线衍射仪和振动样品磁强计对磁性纳米颗粒的掺杂进行了表征,结果表明磁性纳米颗粒已经成功地嵌入到聚合物基质中。
This study describes the use of photo-initiated miniemulsion polymerization of methyl methacrylate and the incorporation of magnetic nanoparticles. With photo-initiator in the oil-in-water miniemulsion, UV irradiation led to the formation of polymer latexes after 15 min with the reaction temperature lower than 45 °C. Moreover, this method can be applied for the incorporation of magnetic nanoparticles. The particle sizes were measured by laser particle analyzer which showed narrow distributions. The morphology of the particles was examined with a transmission electron microscope and scanning electron microscope. The incorporation of magnetic nanoparticles was characterized with X-ray diffraction and vibrating sample magnetometer, both of which demonstrated that magnetic nanoparticles had been successfully incorporated into the polymer matrix.
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