Experimental study of Fe–Mg partitioning and zoning during rapid growth of olivine in Hawaiian tholeiites
Experimental study of Fe–Mg partitioning and zoning during rapid growth of olivine in Hawaiian tholeiites
复制标题
夏威夷拉斑斑斑斑玄斑岩中橄榄石快速生长过程中Fe-Mg分配与分带的实验研究
DOI:
10.1007/s00410-022-01969-8
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发表时间:
2022
影响因子:
3.5
通讯作者:
J. Mourey, Adrien
中科院分区:
文献类型:
--
作者:
Shea, Thomas;K. Matzen, Andrew;J. Mourey, Adrien
The partitioning behavior of Fe and Mg between olivine and basalt melt is of key importance to the study of terrestrial and extraterrestrial basalts. Olivine-melt partitioning studies generally focus on near-equilibrium crystallization conditions. Recent works highlight the tendency for both experimental and natural olivine to grow rapidly, possibly under non-equilibrium conditions. To better understand whether kinetic effects (e.g. boundary layer formation) can influence Fe–Mg partitioning and the development of zoning during rapid crystal growth, we use series of rapid cooling experiments involving a natural Hawaiian tholeiite as starting composition. Experimental charges were held at superliquidus conditions and cooled rapidly to final temperatures corresponding to undercoolings of 10–100 ºC. Overall, we find that within the parameter space of our experiments, rapid growth has largely negligible effects on both Fe–Mg partitioning and zoning patterns. These results are most applicable to relatively crystal-poor natural magmas undergoing a sudden thermal or chemical perturbation. We combine all experiments performed on natural Hawaiian tholeiites to propose a revised MgO-in-glass thermometer applicable to the temperature rangeT= 1060–1500 ºC: T (ºC) = 21.2 × MgO (wt.%) + 1017 ± 13. The Fe–Mg olivine-melt distribution coefficient obtained by combining the different experimental datasets on Hawaiian basalt is= 0.335 ± 0.01, confirming recent conclusions thatis higher than the canonical value of 0.3. Kinetic models of boundary layer formation indicate that the geometry of the propagating crystal-melt interface (infinite planar, spherical, skeletal tip) partly controls olivine zoning or lack thereof. Skeletal branching generally leads to less zoning because boundary layers are more easily dissipated. We also show that crystal nucleation style (continuous vs. instantaneous) after a thermodynamic perturbation may dictate the capacity for individual crystals to develop strong or weak Fe–Mg zoning.
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DOI:
10.1029/2021gc010046
发表时间:
2022
期刊:
Geosystems
影响因子:
--
作者:
Wieser, Penny E.;Edmonds, Marie;Gansecki, Cheryl;Maclennan, John;Jenner, Frances E.;Kunz, Barbara;Antoshechkina, Paula;Trusdell, Frank;Lee, R. L.
通讯作者:
Lee, R. L.
影响因子:
3.5
作者:
T. L. Wright;R. T. Helz
通讯作者:
R. T. Helz
DOI:
--
发表时间:
2009
期刊:
影响因子:
--
作者:
J. Riker;K. Cashman;J. Kauahikaua;Charlene M. Montierth
通讯作者:
Charlene M. Montierth
影响因子:
3.1
作者:
Xiaofei Pu;G. Moore;R. Lange;Jack P. Touran;J. Gagnon
通讯作者:
J. Gagnon
影响因子:
2.9
作者:
A. Lasaga
通讯作者:
A. Lasaga