Mixture of poly(ethylene glycol) and water as environmentally friendly media for efficient enantioselective transfer hydrogenation and catalyst recycling
Mixture of poly(ethylene glycol) and water as environmentally friendly media for efficient enantioselective transfer hydrogenation and catalyst recycling
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聚乙二醇和水的混合物作为环保介质，用于高效的对映选择性转移氢化和催化剂回收
DOI：
10.1016/j.molcata.2007.05.029
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发表时间：
2007-09
影响因子：
--
通讯作者：
中科院分区：
文献类型：
--
作者：
The asymmetric transfer hydrogenation of nonfunctionalized aromatic ketones catalyzed by Ru-TsDPEN was performed successfully in a mixture of poly(ethylene glycol) (PEG) and water. High activity and enantioselectivity were obtained, which were better than or comparable to those obtained in conventional organic solvents. The unmodified catalyst could be easily recovered after extraction of the reduced product with a less polar solvent such as hexane, and was reused at least 14 times without obvious loss in enantioselectivity. These results indicate that the inexpensive and non-toxic aqueous PEG can serve as a new means for the immobilization of Ru-TsDPEN catalyst and related variants without calling for catalyst modification.
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影响因子：
9.8
作者：
P. Andrews;Anna C. Peatt;C. Raston
通讯作者：
P. Andrews;Anna C. Peatt;C. Raston
影响因子：
15
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Q. Fan;C. Ren;C. Yeung;Wenhao Hu;A. Chan
影响因子：
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影响因子：
2.1
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S. Chandrasekhar;N. Reddy;S. Sultana;Ch. Narsihmulu;K. V. Reddy
影响因子：
2.6
作者：
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Carlos Kleber Z. Andrade and Luana M. Alves