Middle distillates hydrogen content via GC×GC-FID.
Middle distillates hydrogen content via GC×GC-FID.
复制标题
通过GC×GC-FID测定中间馏分氢含量。
DOI：
10.1016/j.talanta.2018.04.059
复制
发表时间：
2018
期刊：
影响因子：
6.1
通讯作者：
Gozdem Kilaz
中科院分区：
文献类型：
--
作者：
P. Vozka;H. Mo;P. Šimáček;Gozdem Kilaz
Liquid transportation fuels in the middle distillate range contain thousands of hydrocarbons making the predictions and calculations of properties from composition a challenging process. We present a new approach of hydrogen content determination by comprehensive two-dimensional gas chromatography with flame ionization detector (GC×GC-FID) using a weighted average method. GC×GC-FID hydrogen determination precision was excellent (0.005 wt% repeatability). The method accuracy was evaluated by high-resolution nuclear magnetic resonance (NMR) technique, which is non-biased, measures the H signal directly and was independently validated by controls in the current study. The hydrogen content (in the range of 12.72–15.54 wt%) in 28 fuel samples were determined using GC×GC-FID. Results were within ± 2% of those obtained via NMR. Owing to the fact that NMR is accepted as an accurate technique for hydrogen content determination, the GC×GC method proposed in this study can be considered precise and accurate.
影响因子：
7.4
作者：
Huaping Mo;Raftery, Daniel
通讯作者：
Raftery, Daniel