Dual-mode optical thermometry based on transparent NaY2F7:Er3+,Yb3+ glass-ceramics

Dual-mode optical thermometry based on transparent NaY2F7:Er3+,Yb3+ glass-ceramics
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基于透明NaY2F7:Er3,Yb3微晶玻璃的双模光学测温

DOI:
10.1016/j.ceramint.2021.10.192
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发表时间:
2021-10
影响因子:
5.2
通讯作者:
Hai Guo
Hai Guo
中科院分区:
材料科学1区
文献类型:
--
作者:
Hailing Gong;Xiusha Peng;Ghulam Abbas Ashraf;FangFang Hu;RongFei Wei;Hai Guo

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采用熔融淬火和热处理工艺制备了高透过率的NaY_2F_7:Er ~(3+),Yb ~(3+)微晶玻璃。通过X射线衍射、透射光谱和上转换发射光谱对样品的结构、形貌和光致发光性能进行了研究。由于热处理后结晶度的提高,GC的上转换发光强度显著高于前体玻璃。探讨了Er 3+离子在热耦合能级(2 H11/2/4S 3/2)和非热耦合能级(2 H11/2/4F 9/2)下的光学测温性能。在323 K时,它们的相对灵敏度(SR)分别为1.00%K − 1和0.76%K − 1。在563 K时,最大测温误差(ΔT)分别为0.09 K和0.12 K,重复性(R)分别超过99%和98%。实验结果表明,NaY_2F_7 GC是一种优良的自校准测温材料,具有上级温度分辨率和重复性。
NaY2F7:Er3+,Yb3+glass-ceramics (GC) with high transmittance were well manufactured using a melt-quenching technique and subsequent thermal treatment. Structure, morphology and photoluminescence properties of all samples were thoroughly studied via X-ray diffraction, transmission and up-conversion emission spectrum. Due to the improved crystallinity after thermal treatment, the up-conversion emission intensity of GC was significantly higher than the precursor glass. The optical thermometry performances of Er3+ions at thermally coupled (2H11/2/4S3/2), and non-thermally coupled energy levels (2H11/2/4F9/2) were explored. Their relative sensitivities (SR) are 1.00% K−1and 0.76% K−1at 323 K, respectively. Moreover, their maximum temperature measurement errors (ΔT) are 0.09 K and 0.12 K at 563 K, with repeatability (R) exceeding 99% and 98%, respectively. All of the findings suggest that NaY2F7GC are excellent self-calibration temperature measuring materials, with superior temperature resolution and repeatability.
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