Synthesis, structure, photophysical and electrochemical properties of a novel metalloporphyrin with a condensed three-dimensional porous open framework

Synthesis, structure, photophysical and electrochemical properties of a novel metalloporphyrin with a condensed three-dimensional porous open framework
复制标题

具有稠密三维多孔开放骨架的新型金属卟啉的合成、结构、光物理和电化学性质

DOI:
10.1016/j.ica.2014.01.037
复制
发表时间:
2014-04
影响因子:
2.8
通讯作者:
Hong-Ru Fu
Hong-Ru Fu
中科院分区:
化学3区
文献类型:
--
作者:
Wen-Tong Chen;Zhi-Gang Luo;Yin-Feng Wang;Xian Zhang;Hong-Ru Fu

文献摘要

参考文献

相似文献

通过溶剂热反应合成了一种新型的4f-3d金属卟啉[EuZn(TPPS)H3 O]n(1)(H2 TPPS =四(4-磺酸基苯基)卟啉),并通过X射线单晶衍射对其结构进行了表征。化合物1具有两种一维(1D)无限长链的三维(3D)结构。化合物1具有223 μ 3的大空隙空间,相当于晶胞体积的9.4%。化合物1显示出高的热稳定性和水稳定性。磁性测量表明化合物1具有反铁磁性。
A novel 4f–3d metalloporphyrin, [EuZn(TPPS)H3O]n(1) (H2TPPS = tetra(4-sulfonatophenyl)porphyrin), has been synthesized via a solvothermal reaction and structurally characterized by single-crystal X-ray diffraction. Compound1features a three-dimensional (3-D) structure with two kinds of one-dimensional (1D) infinite chains. Based on the condensed 3-D porous open framework, compound1has a large void space of 223 Å3, corresponding to 9.4% of the unit-cell volume. Compound1shows high thermal and aqueous stability. Magnetic measurements reveal that compound1has an antiferromagnetic behavior.
DOI: 10.1002/9783527618248.ch19
发表时间: 2008-04
期刊: ChemInform
影响因子: --
作者:
S. Fukuzumi;D. Guldi
通讯作者: S. Fukuzumi;D. Guldi
DOI: 10.1002/anie.200803543
发表时间: 2008-01-01
影响因子: 16.6
作者:
Bar, Arun Kumar;Chakrabarty, Rajesh;Mukherjee, Partha Sarathi
通讯作者: Mukherjee, Partha Sarathi
DOI: 10.1039/c2dt11989g
发表时间: 2012-03
影响因子: 4
作者:
Chao Zou;Chuande Wu
通讯作者: Chao Zou;Chuande Wu
DOI: 10.1021/ja0621086
发表时间: 2006-08-09
影响因子: 15
作者:
Loiseau, Thierry;Lecroq, Ludovic;Latroche, Michel
通讯作者: Latroche, Michel
DOI: 10.1021/ja807847q
发表时间: 2009-02-25
影响因子: 15
作者:
Pan Z;Wang Q;Sheng X;Horner JH;Newcomb M
通讯作者: Newcomb M