Smart Supramolecular Self-Assembled Nanosystem: Stimulus-Responsive Hydrogen-Bonded Liquid Crystals.

Smart Supramolecular Self-Assembled Nanosystem: Stimulus-Responsive Hydrogen-Bonded Liquid Crystals.
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智能超分子自组装纳米系统:刺激响应氢键液晶

DOI:
10.3390/nano11020448
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发表时间:
2021-02-10
期刊:
Nanomaterials (Basel, Switzerland)
影响因子:
--
通讯作者:
Zhou G
Zhou G
中科院分区:
其他
文献类型:
--
作者:
Liu B;Yang T;Mu X;Mai Z;Li H;Wang Y;Zhou G

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在液晶状态下,液晶分子的特定取向和排列在结构和性质上产生突出的各向异性,随后产生多种光电功能。除了有机液晶分子,其他非经典组分,包括无机纳米材料,能够通过非共价相互作用自组装成取向的超分子液晶中间相。特别是这些组分在尺寸、形状、结构和性质上的巨大差异赋予LC超分子更高的各向异性和可行性。因此,氢键由于其高选择性和方向性而被认为是超分子液晶的最佳和最常见的选择。本文综述了超分子氢键液晶纳米体系在自组装结构、刺激响应能力和应用等方面的最新进展,为液晶技术的发展提供了新的、巨大的潜力。
In a liquid crystal (LC) state, specific orientations and alignments of LC molecules produce outstanding anisotropy in structure and properties, followed by diverse optoelectronic functions. Besides organic LC molecules, other nonclassical components, including inorganic nanomaterials, are capable of self-assembling into oriented supramolecular LC mesophases by non-covalent interactions. Particularly, huge differences in size, shape, structure and properties within these components gives LC supramolecules higher anisotropy and feasibility. Therefore, hydrogen bonds have been viewed as the best and the most common option for supramolecular LCs, owing to their high selectivity and directionality. In this review, we summarize the newest advances in self-assembled structure, stimulus-responsive capability and application of supramolecular hydrogen-bonded LC nanosystems, to provide novel and immense potential for advancing LC technology.
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发表时间: 2016-02-24
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