Mechanochemically activated synthesis of zirconium carbide nanoparticles at room temperature: A simple route to prepare nanoparticles of transition metal carbides

Mechanochemically activated synthesis of zirconium carbide nanoparticles at room temperature: A simple route to prepare nanoparticles of transition metal carbides
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室温下机械化学活化合成碳化锆纳米颗粒:制备过渡金属碳化物纳米颗粒的简单途径

DOI:
10.1016/j.jeurceramsoc.2011.01.022
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发表时间:
2011-07
影响因子:
5.7
通讯作者:
--
中科院分区:
材料科学1区
文献类型:
--
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采用甲苯球磨法制备了碳化锆纳米颗粒。研究发现,铣削时间可以调节C与Zr的比值。火花等离子烧结实验表明,在1200℃的低温下,zrcx纳米颗粒可以实现致密化。该方法已成功制备了WCx、TiCx和NbCx纳米颗粒,证明了该方法是制备过渡金属碳化物纳米颗粒的可行途径。
Mechanically activated syntheses of zirconium carbides (ZrCx) nanoparticles have been performed via ball milling of Zr powder with toluene. It has been found that the milling time can be used to tune the ratio x of C to Zr. The spark plasma sintering of the ZrCxnanoparticles has shown that the densification can be achieved at a considerably reduced temperature of 1200°C. This ball milling procedure has been tried to successfully synthesize the nanoparticles of WCx, TiCx, and NbCx, demonstrating that it is a potential route to prepare the nanoparticles of transition metal carbides.
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