Suzuki-miyaura cross-coupling in acylation reactions, scope and recent developments.
Suzuki-miyaura cross-coupling in acylation reactions, scope and recent developments.
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铃木 - 米龙在酰化反应，范围和最新发展中的交叉偶联。
DOI：
10.3390/molecules18011188
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发表时间：
2013-01-17
期刊：
影响因子：
--
通讯作者：
Venturello P
中科院分区：
文献类型：
--
作者：
Blangetti M;Rosso H;Prandi C;Deagostino A;Venturello P
自第一份报告以来，铃木-宫浦(Suzuki-Miyaura，SM)交叉偶联反应因其简便易行和范围广泛，已成为世界各地许多实验室的常规方法。对于其他常见的过渡金属催化的交叉偶联反应，SM反应作为将酰基功能引入特定底物的工具到目前为止还很少被利用。在这篇综述中，将从直接SM酰化偶联到硼酸盐与酰氯或酸酐之间的交叉偶联的最新进展，对文献中发现的各种方法进行讨论。将特别注意使用掩蔽的酰基硼酸盐、烷氧基苯乙烯基和烷氧基二烯基硼酸酯作为偶联伙伴。最后一节将重点介绍作为天然产物合成框架中关键合成步骤的酰基SM反应。
Since the first report and due to its handiness and wide scope, the Suzuki-Miyaura (SM) cross coupling reaction has become a routine methodology in many laboratories worldwide. With respect to other common transition metal catalyzed cross couplings, the SM reaction has been so far less exploited as a tool to introduce an acyl function into a specific substrate. In this review, the various approaches found in the literature will be considered, starting from the direct SM acylative coupling to the recent developments of cross coupling between boronates and acyl chlorides or anhydrides. Special attention will be dedicated to the use of masked acyl boronates, alkoxy styryl and alkoxy dienyl boronates as coupling partners. A final section will be then focused on the acyl SM reaction as key synthetic step in the framework of natural products synthesis.
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通讯作者：
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作者：
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通讯作者：
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