Fe3O4 decorated graphene/poly(vinylidene fluoride) nanocomposites with high dielectric constant and low dielectric loss

Fe3O4 decorated graphene/poly(vinylidene fluoride) nanocomposites with high dielectric constant and low dielectric loss
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Fe3O4修饰石墨烯/聚偏二氟乙烯纳米复合材料具有高介电常数和低介电损耗

DOI:
10.1016/j.compscitech.2018.12.022
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发表时间:
2019-02
影响因子:
9.1
通讯作者:
Mai Yiu Wing
Mai Yiu Wing
中科院分区:
材料科学1区
文献类型:
--
作者:
Li Yuchao;Zhang Dongmei;Wang Shuangshuang;Zhan Yanhu;Yin Jie;Tao Xuquan;Ge Xiangcai;Tjong Sie Chin;Liu Hong Yuan;Mai Yiu Wing

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Percolative poly(vinylidene fluoride) (PVDF) composites with high dielectric constant and low dielectric loss was successfully achieved by incorporating reduced graphene oxide (rGO) decorated with magnetic iron oxide (Fe3O4) (rGO@Fe3O4) nano-fillers. The morphology, structure, thermal, electrical and magnetic properties of the composites were investigated systematically by using SEM, XRD, FTIR, TGA, DSC, impedance analyzer and magnetometer, respectively. The presence of a tiny amount of poly(sodium 4-styrene sulfonate) (PSSNa) facilitated the homogeneous distribution of rGO@Fe3O4nanoparticles and prevented the formation of an electrical conductive network within the PVDF matrix, resulting in an excellent dielectric performance of the rGO@Fe3O4/PVDF nano-composites. With 1.0 wt% rGO@Fe3O4incorporated in PVDF, the nanocomposite exhibited a high dielectric constant of 1297 and a low dielectric loss of 0.26 at 100 Hz. Percolation model revealed that such improvements could be attributed to the synergistic effect of the inorganic Fe3O4and rGO, whereby the electric charges were accumulated by forming many mini-capacitors in the bulk PVDF matrix. The structure-property behavior of the final nanocomposites was discussed.
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