Experiments on n-heptane combustion with two types of catalyst layouts

Experiments on n-heptane combustion with two types of catalyst layouts
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两种催化剂布局正庚烷燃烧实验

DOI:
10.1016/j.applthermaleng.2016.02.010
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发表时间:
2016-05
影响因子:
6.4
通讯作者:
Cen Kefa
Cen Kefa
中科院分区:
工程技术2区
文献类型:
--
作者:
Yang Weijuan;Zhou Mingyue;Deng Chen;Huang Tiao;Zhou Junhu;Wang Zhihua;Liu Jianzhong;Cen Kefa

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在填充床微型燃烧器中使用两种催化剂布局,即连续(A型)和两段式(B型)类型,进行正庚烷燃烧。采用铈锆固溶体负载铂作为催化剂。两种燃烧室由于催化剂布置的不同而表现出不同的燃烧特性。B型显著扩大了稳定燃烧的雷诺数(Re)上限,在当量比Φ= 1.6的富油工况下,Re = 1500时保持稳定燃烧。A型在低Revalues时更有利,低Relimit降低到12。A型和B型的壁温分布分别为单峰和双峰。B型的双峰分布不仅减缓了壁温随Re的变化,而且证明了喉部发生了无催化剂的均质燃烧。由于燃烧过程的不同,A型煤与B型煤相比,其产物沿着长度方向的变化趋势不同。此外,两种类型的转化率在Re = 160时达到最大值(84.4%和88.3%)。B型转化率高的原因是多相/均相燃烧和较长的热回流区。
n-Heptane combustion was conducted in packed-bed micro combustors using two catalyst layouts, namely, continuous (type A) and two-sectional (type B) types. Cerium–Zirconium solid solution-supported platinum was adopted as catalyst. The two combustors demonstrated distinct combustion characteristics owing to their different catalyst layouts. Type B significantly expanded the upper limit of Reynolds number (Re) of stable combustion, maintaining stable combustion atRe= 1500 under fuel-rich conditions at an equivalent ratio ofΦ= 1.6. Type A was more advantageous at lowRevalues, and the lowerRelimit was reduced to 12. Types A and B displayed a single peak and a bimodal distribution of wall temperature, respectively. The bimodal distribution in type B not only slowed down the variation in wall temperature withRebut also proved that catalyst-free homogenous combustion occurred in the throat. As a result of the different combustion processes, type A showed different variation trends of products along the length compared with type B. Moreover, the conversion rates of the two types reached their maximum values (84.4% and 88.3%) atRe= 160. High conversion rate of type B was attributed to heterogeneous/homogenous combustion and long heat reflux zones.
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