Mechanistic and Analytical Studies in Organic Electrochemistry

有机电化学的机理和分析研究

• 批准号: 8722764
• 负责人: Dennis Evans
• 金额: $ 34.92万
• 依托单位: University of Delaware
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1988
• 资助国家: 美国
• 起止时间: 1988-03-15 至 1991-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=8722764&HistoricalAwards=false
• 关键词: Mechanistic; Analytical; Studies; Organic; Electrochemistry

This project is in the general area of analytical and surface chemistry and in the subfield of organic electrochemistry. The thrust of this research program is to find how conformational change and isomerization affect or are affected by electron transfer reactions. The studies will focus upon organic and organometallic molecules for which conformational change and/or isomerization reactions are expected to be important. The project will also assess the importance of structural and environmental factors in governing the energetics and kinetics of electron transfer reactions, both at the electrode surface and in solution. Some of the research effort will be directed to the improvement of measurement techniques and the development of new methods. The results of these investigations will aid in understanding biological electron transfer processes and electrochemical energy storage and conversion.

这个项目是在一般地区的分析和表面 化学和有机电化学的子领域。 的 这项研究计划的主旨是找到构象如何 变化和异构化影响电子或受电子影响 转移反应 这些研究将集中在有机和 有机金属分子，其构象变化和/或 预计异构化反应是重要的。 的 项目还将评估结构和 控制能量学和动力学的环境因素 电子转移反应，在电极表面 在溶液中。 一些研究工作将直接 测量技术的改进， 开发新方法。 这些调查的结果将有助于理解 生物电子传递过程和电化学 能量储存和转换。