Synthesis and Characterization of Transition Metal Trihydrogen Complexes

过渡金属三氢配合物的合成与表征

• 批准号: 8814191
• 负责人: D. Michael Heinekey
• 金额: $ 13.8万
• 依托单位: Yale University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1988
• 资助国家: 美国
• 起止时间: 1988-09-01 至 1991-05-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=8814191&HistoricalAwards=false
• 关键词: Synthesis; Characterization; Transition; Metal; Trihydrogen

This award from the Inorganic, Bioinorganic and Organometallic Chemistry Program is in the area of organometallic chemistry. The goals of the project are to provide additional direct experimental evidence for the recently discovered transition metal complexes of the trihydrogen cation, to establish the structures of these complexes, and to synthesize additional examples of such complexes. Structural information will be obtained by a combination of solution and solid state NMR spectroscopy, variable temperature IR spectroscopy, and X-ray and neutron diffraction. The results of this project will be relevant to industrially important hydrogenation reactions and will provide new challenges to theoreticians who are concerned with chemical bonding.

这一奖项来自无机化学、生物无机化学和金属有机化学项目，是金属有机化学领域的奖项。该项目的目标是为最近发现的三氢阳离子过渡金属络合物提供更多的直接实验证据，建立这些络合物的结构，并合成更多的此类络合物的例子。结构信息将通过溶液和固体核磁共振光谱、变温红外光谱以及X射线和中子衍射的组合获得。该项目的结果将与工业上重要的加氢反应相关，并将向关注化学键的理论家提出新的挑战。