Purchase of an Automated X-Ray Diffractometer

购买自动 X 射线衍射仪

• 批准号: 8912675
• 负责人: Derek Hodgson
• 金额: $ 12.4万
• 依托单位: University of Wyoming
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1989
• 资助国家: 美国
• 起止时间: 1989-07-15 至 1990-12-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=8912675&HistoricalAwards=false
• 关键词: Purchase; Automated; Ray; Diffractometer

The technique of X-ray crystallography is a powerful tool for the determination of the molecular structure of compounds as diverse as small polypeptides and complex metal clusters. When combined with the latest computer software, the technique is becoming remarkably easy to put into practice. Access to X-ray crystallographic instrumentation markedly improves the ability of chemists to carry out frontier research. The Department of Chemistry at the University of Wyoming will use this award from the Chemical Instrumentation Program to help acquire an automated X-ray diffractometer. The areas of chemical research that will be enhanced by the acquisition are as follows: 1) Design and synthesis of binuclear manganese complexes 2) Design and synthesis of new inorganic clusters 3) Ligation properties of chelating fluoroalkylphosphines 4) Asymmetric alkylation of carbamate alpha-oxocarbanions 5) Vesicles derived from cleavable double-chain surfactant- based vesicles 6) Photooxidation of sulfur-containing protein.

X 射线晶体学技术是确定小多肽和复杂金属簇等多种化合物分子结构的有力工具。 当与最新的计算机软件相结合时，该技术变得非常容易付诸实践。 使用 X 射线晶体学仪器显着提高了化学家开展前沿研究的能力。 怀俄明大学化学系将利用化学仪器项目的​​这一奖项来帮助购买自动 X 射线衍射仪。 此次收购将增强化学研究领域如下： 1) 双核锰配合物的设计和合成 2) 新型无机簇的设计和合成 3) 螯合氟烷基膦的连接特性 4) 氨基甲酸酯 α-氧代碳负离子的不对称烷基化 5) 可裂解双链表面活性剂基衍生的囊泡 囊泡 6) 含硫蛋白质的光氧化。