Spectroscopic Study of Transition Metal Complexes in Hydrothermal Solutions

水热溶液中过渡金属配合物的光谱研究

• 批准号: 8917292
• 负责人: Donald McClure
• 金额: $ 30万
• 依托单位: Princeton University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1990
• 资助国家: 美国
• 起止时间: 1990-02-15 至 1993-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=8917292&HistoricalAwards=false
• 关键词: Spectroscopic; Study; Transition; Metal; Complexes

This project will study the Raman and electronic spectra of selected transition metal complex ions in aqueous solutions to determine their molecular structure and thermodynamic properties at the conditions of formation of hydrothermal ore deposits. This work is also of fundamental chemical interest because relatively little is known about the physical chemistry of concentrated electrolyte solutions at higher temperatures and pressures. The proposed research is part of a continuing collaborative project involving the Chemistry and Geology Departments at Princeton.

本项目将研究选定的过渡金属络合离子在水溶液中的拉曼光谱和电子光谱，以确定它们在热液矿床形成条件下的分子结构和热力学性质。这项工作还具有基本的化学意义，因为人们对较高温度和压力下浓缩电解质溶液的物理化学知之甚少。这项拟议的研究是普林斯顿化学和地质系持续合作项目的一部分。