Free Radical and Photochemical Reactions of OrganophosphorusSystems

这项来自有机动力学项目的拨款支持了犹他大学卫斯理·g·本特鲁德博士的持续工作。这项研究将使人们对有机磷化合物反应的基本过程有更好的了解。本特鲁德博士将进行的实验将集中于三价和五价有机磷衍生物的光化学和自由基反应。努力将旨在获得对完整四价磷酰自由基反应的新认识。光谱和产物研究将被用来定义这些自由基导致结构新颖产物的反应的范围、机制和结构-反应模式。

This grant from the Organic Dynamics Program supports the continuing work of Dr. Wesley G. Bentrude at the University of Utah. The investigation will result in an improved understanding of the fundamental processes involved in reactions of organic phosphorus compounds. The experiments to be carried out by Dr. Bentrude will focus on photochemical and free radical reactions of both tricovalent and pentacovalent organophosphorus derivatives. Efforts will be aimed at gaining a new understanding of the reactions of intact tetracovalent phosphoranyl radicals. Spectroscopic and product studies will be employed to define the scope, mechanism, and structure-reactivity patterns of reactions in which these radicals lead to structurally novel products.