Free Radical and Photochemical Reactions of OrganophosphorusSystems

有机动力学计划的这笔赠款支持 Wesley G博士的工作本特鲁德在牛津大学 犹他州。 调查将导致改善 了解参与的基本过程， 有机磷化合物的反应。 本特鲁德博士将进行的实验将集中在 光化学和自由基反应， 和五价有机磷衍生物。 努力将 目的是对化学反应有一个新的认识， 完整的四价正膦基。 光谱和 将采用产品研究来确定范围， 反应机理和结构-反应性模式， 这些基团导致结构新颖的产物。

This grant from the Organic Dynamics Program supports the continuing work of Dr. Wesley G. Bentrude at the University of Utah. The investigation will result in an improved understanding of the fundamental processes involved in reactions of organic phosphorus compounds. The experiments to be carried out by Dr. Bentrude will focus on photochemical and free radical reactions of both tricovalent and pentacovalent organophosphorus derivatives. Efforts will be aimed at gaining a new understanding of the reactions of intact tetracovalent phosphoranyl radicals. Spectroscopic and product studies will be employed to define the scope, mechanism, and structure-reactivity patterns of reactions in which these radicals lead to structurally novel products.