Synthesis and Characterization of Transition-Metal Chalcogenides

过渡金属硫属化物的合成与表征

• 批准号: 9114934
• 负责人: James Ibers
• 金额: $ 63.34万
• 依托单位: Northwestern University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1992
• 资助国家: 美国
• 起止时间: 1992-04-01 至 1996-11-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9114934&HistoricalAwards=false
• 关键词: Synthesis; Characterization; Transition; Metal; Chalcogenides

This research is concerned with the synthesis and characterization of solid-states, transition-metal compound having S, Se, or Te. The ultimate goal is to make the chemistry of solid-state material more predictable. The chemistry of the proposed compounds is fundamentally different from that of the oxides. Characterization of the new materials will involve structure determination by single-crystal x-ray method, measurement of transport properties such as electrical conductivity and magnetic susceptibility, and approximate electronic calculation for simple structures. Three major areas are studied: 1) oxyselenides and oxysulfides, 2) Nb or Ta/ transition metal/Te systems, and the reactive flux technique for the synthesis of new ternary and quaternary solid-state compound.

本研究涉及的合成和表征 具有S、Se或Te的固态过渡金属化合物。 最终目标是使固态材料的化学 更容易预测。 所提出的化合物的化学性质是 与氧化物有本质的不同。 表征 的新材料将涉及结构确定， 单晶x射线法，输运性质测量 例如电导率和磁化率， 简单结构的近似电子计算。 三 研究的主要领域：1）氧硒化物和氧硫化物，2）铌或 Ta/过渡金属/Te体系及反应助熔剂技术 用于合成新的三元和四元固态 化合物.