Synthesis, Structure and Reactivity of Metal Complexes With Sterically Demanding Chalcogenolate Ligands

具有空间要求的硫属醇盐配体的金属配合物的合成、结构和反应性

• 批准号: 9210406
• 负责人: John Arnold
• 金额: $ 22.66万
• 依托单位: University of California-Berkeley
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1992
• 资助国家: 美国
• 起止时间: 1992-08-01 至 1995-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9210406&HistoricalAwards=false
• 关键词: Synthesis; Structure; Reactivity; Metal; Complexes

This project, funded by the Inorganic, Bioinorganic and Organo-metallic Chemistry Program, involves the study of tellurolate and selenolate ligands with both main group and transition metal centers. The focus is on ligands that contain bulky alkyl, silyl or aryl substituents such that monomeric complexes are formed. Studies of the reactivity of these complexes will include chalcogenide displacement/substitution, insertions into the M-ER (E = Te, Se) bond, reactions of the E center, and cleavage of the E-R bond. The long term objective of the research is to put this chemistry on the same basis as the much studied alkoxide and sulfide congeners. The potential for use of the molecular chalcogenide compounds as precursors for solid-state, materials will be examined as part of the project. %%% This project involves the study of the fundamental chemistry of selenium and tellurium. Unlike the lighter elements in this family (the chalcogenides), relatively little attention has been given to the molecular chemistry of these elements, primarily because of the difficulty of working with them. This is in spite of the fact that they are constituents of technologically important devices such as infrared detectors rechargeable batteries, photothermic imaging materials and photovoltaic solar cells to name a few. Professor Arnold, an excellent synthetic inorganic chemist, has laid the groundwork that could lead to some exciting advances in the chemistry of these elements and potentially to advances in technology arenas as well.

该项目由无机，生物无机和 有机金属化学计划，涉及研究 碲酸盐和硒酸盐配体， 过渡金属中心 重点是配体， 大体积的烷基、甲硅烷基或芳基取代基， 形成复合物。 研究这些反应性 络合物将包括硫族化物置换/取代， 插入到M-ER（E = Te，Se）键中，E 中心和E-R键的断裂。 长期目标 研究的重点是将这种化学反应置于 研究较多的醇盐和硫化物同系物。 的潜在 对于使用分子硫属化物化合物作为前体 对于固态，材料将作为 项目 %%% 该项目涉及的基础化学的研究 硒和碲。 不像这里面较轻的元素 家庭（硫属化物），相对较少的关注， 这些元素的分子化学 主要是因为与他们合作的困难。 这 尽管他们是 红外探测器等重要技术设备 可充电电池、光热成像材料和 光伏太阳能电池仅举几例。 阿诺德教授， 一位出色的无机合成化学家， 这可能会导致一些令人兴奋的化学进步， 这些元素和潜在的技术领域的进步 也