CVD Preparation of Hydrogen Semipermeable Metallic-Ceramic Membrane Composites

氢气半透金属陶瓷膜复合材料的CVD制备

• 批准号: 9216164
• 负责人: Jerry Lin
• 金额: $ 10.52万
• 依托单位: University of Cincinnati Main Campus
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1993
• 资助国家: 美国
• 起止时间: 1993-07-01 至 1996-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9216164&HistoricalAwards=false
• 关键词: CVD; Preparation; Hydrogen; Semipermeable; Metallic

This study attempts to develop a membrane for use in the high temperature separation of hydrogen from a gaseous mixture. For high temperature applications, inorganic membranes are necessary, and palladium and palladium silver alloy metal membranes exhibit the highest selectivity for hydrogen. The problems with these metallic membranes are that temperature or pressure cycles can cause them to crack, and their surfaces can be poisoned by sulfur containing molecules in the gaseous mixture. To avoid cracking, metallic membranes are usually fabricated to large thicknesses which imparts a structural rigidity. However large membrane thicknesses lower the flux to the point where the use of thick membranes becomes economically unattractive. In order to develop a membrane with high flux and selectivity, the study suggests forming membranes in which metallic Pd and Pd/Ag films have been placed inside the pores of a macroporous ceramic substrate. Two types of porous ceramic membranes will be used. The first is a one layer . alumina disk with a pore diameter in the range of .2 - .7 >m. The second is a two layer disk consisting of a thin (5>m), small pore (5 nm) layer lanthana modified y Al2O3 layer atop a thick (1-2 mm), large pore (.2 - .7 >m) . alumina support. The metal will be placed in the ceramic support by using a CVD counterdiffusion process in which PdCl2 or a mixture of PdCl2 and AgBr will diffuse through the pores from one face of the ceramic support and H2 will diffuse from the opposite face. When the gases meet somewhere inside the membrane, the reduction reactions: PdCl2(g) + H2(g) --- Pd(s) + 2HCl(g) AgBr(g) + 1/2 H2(g) --- Ag(s) + HBr(g) will produce the metal (or metal alloy) which will span the interstitial space of the pore and form a gas tight layer. The layers, supported by the ceramic membrane, should be more durable and less susceptible to chemical attack.

本研究试图开发一种用于从气体混合物中高温分离氢的膜。对于高温应用，无机膜是必要的，钯和钯银合金金属膜对氢表现出最高的选择性。这些金属膜的问题是，温度或压力循环可能导致它们破裂，它们的表面可能被气体混合物中含有硫的分子毒害。为了避免开裂，金属膜通常被制造成很大的厚度，这赋予了结构刚度。然而，大的膜厚度降低通量，使使用厚膜在经济上变得没有吸引力。为了开发具有高通量和选择性的膜，研究建议在大孔陶瓷衬底的孔内放置金属Pd和Pd/Ag膜。将使用两种类型的多孔陶瓷膜。第一层是单层的。氧化铝盘的孔径在。2 - 0.7立方米第二种是双层圆盘，由一层薄的（5>m）、小孔隙（5nm）的镧修饰Al2O3层组成，上面有一层厚的（1- 2mm）、大孔隙（5nm）。2 - 0.7立方米)。氧化铝的支持。金属将通过CVD反扩散过程放置在陶瓷支架中，其中PdCl2或PdCl2和AgBr的混合物将从陶瓷支架的一面扩散通过孔隙，而H2将从相反的一面扩散。当气体在膜内的某个地方相遇时，还原反应：PdCl2(g) + H2(g)—Pd(s) + 2HCl(g) AgBr(g) + 1/2 H2(g)—Ag(s) + HBr(g)将生成金属（或金属合金），该金属（或金属合金）将跨越孔隙间隙并形成气密层。​由陶瓷膜支撑的层应该更耐用，更不易受到化学侵蚀。